首页> 外国专利> METHOD OF PREPARING METHACRYLATE-BASED POLYMER USING FREE RADICAL POLYMERIZATION REACTION BY VISIBLE LIGHT PHOTOCATALYSIS

METHOD OF PREPARING METHACRYLATE-BASED POLYMER USING FREE RADICAL POLYMERIZATION REACTION BY VISIBLE LIGHT PHOTOCATALYSIS

机译:可见光催化自由基聚合制备甲基丙烯酸酯的方法。

摘要

PURPOSE: A manufacturing method for a methacrylate-based polymer is provided to easily control the molecular weight of a polymethylmethacrylate by controlling the mixing ratio of a monomer and an initiator. CONSTITUTION: A manufacturing method for a methacrylate-based polymer comprises a step of irradiating the mixture of a radical initiator, electron donor, monomer, ruthenium dye, and solvent with visible rays. The ruthenium dye is a ruthenium(II) polypyridine complex. The radical initiator is -haloester, benzyl halide, or a combination thereof. The contents of the electron donor, monomer, ruthenium dye, and radical initiator are respectively 0.25-10 mol, 0.005-0.1 mol, and 0.25-5 mol based on 100 mol of the monomer.
机译:目的:提供一种甲基丙烯酸酯类聚合物的制造方法,以通过控制单体和引发剂的混合比来容易地控制聚甲基丙烯酸甲酯的分子量。组成:一种基于甲基丙烯酸酯的聚合物的制造方法,包括以下步骤:用可见光照射自由基引发剂,电子给体,单体,钌染料和溶剂的混合物。钌染料是钌(II)聚吡啶配合物。自由基引发剂是-卤代酸酯,苄基卤或它们的组合。基于100摩尔的单体,电子给体,单体,钌染料和自由基引发剂的含量分别为0.25-10摩尔,0.005-0.1摩尔和0.25-5摩尔。

著录项

  • 公开/公告号KR101287546B1

    专利类型

  • 公开/公告日2013-07-31

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20110084645

  • 发明设计人 최원용;장관;

    申请日2011-08-24

  • 分类号C08F20/10;C08F2/48;C08F2/44;C08F2/38;

  • 国家 KR

  • 入库时间 2022-08-21 16:24:49

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