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COMPOSITE MATERIAL FOR LIQUID RADIOACTIVE WASTE IMMOBILIZATION AND METHOD OF ITS APPLICATION

机译:液体放射性废物固定化的复合材料及其应用方法

摘要

FIELD: power industry.;SUBSTANCE: invention refers to processing technology of high-salty liquid radioactive wastes of low and medium activity level, which contain up to 30% of organic substances by their being added to magnesite cement. Composite material has the following composition: loose dead-burned magnesite caustic powder - 27-28 wt %, hard salts - 5-6 wt %, calcium chloride (CaCl2) - 0.1-6 wt %, catalytic carbon-bearing additive - 0.1-0.2 wt %; potassium ferrocyanide solution - 0.05-0.1 wt %; and nickel nitrate solution - 0.05-0.1 wt %, and liquid radioactive wastes are the rest. The following sequence of ingredients is added to liquid radioactive wastes: hard salts, potassium ferrocyanide solution, nickel nitrate solution, calcium chloride, catalytic carbon-bearing additive, and loose dead-burned magnesite caustic powder. The invention allows obtaining compounds meeting the main requirements of their quality as per GOST R 51883-2002 (cesium leaching rate -137 ≤1-10-3, achieved - 2-10-5g/cm2·day, and compressive mechanical strength ≥5 MPa), with filling of dry radioactive layers of up to 37 wt %.;EFFECT: compliance with the main requirements.;2 cl
机译:领域:本发明涉及低和中等活度水平的高盐液体放射性废物的处理技术,其通过添加到菱镁矿水泥中最多包含30%的有机物质。复合材料具有以下成分:松散的死燃烧的菱镁矿苛性粉-27-28 wt%,硬盐-5-6 wt%,氯化钙(CaCl 2 )-0.1-6 wt%,催化含碳添加剂-0.1-0.2 wt%;亚铁氰化钾溶液-0.05-0.1 wt%;硝酸镍溶液-0.05-0.1 wt%,其余为液态放射性废物。将以下顺序的成分添加到液态放射性废物中:硬盐,亚铁氰化钾溶液,硝酸镍溶液,氯化钙,催化性含碳添加剂和散死的菱镁矿苛性粉。本发明允许获得符合GOST R 51883-2002的主要质量要求的化合物(铯的浸出率-137≤1-10 -3 ,达到-2-10 -5 < / Sup> g / cm 2 ·天,抗压机械强度≥5MPa),干放射性层的填充量最高为37 wt%。;效果:符合主要要求。2 CL

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