首页> 外国专利> Vinyl chloride resin paste composition useful for inoculation emulsion polymerization, comprises an anionic surfactant, cationic surfactant, polymerization initiator, and inoculum

Vinyl chloride resin paste composition useful for inoculation emulsion polymerization, comprises an anionic surfactant, cationic surfactant, polymerization initiator, and inoculum

机译:用于接种乳液聚合的氯乙烯树脂糊剂组合物,其包含阴离子表面活性剂,阳离子表面活性剂,聚合引发剂和接种物

摘要

Vinyl chloride resin paste composition comprises (in parts by weight): an anionic surfactant (0.2-2), a cationic surfactant (0.005-0.05), a polymerization initiator (0.01-1), and inoculum (1-10), based on a vinyl chloride monomer (100). An independent claim is also included for producing vinyl chloride resin paste with improved polymerization heat control, comprising subjecting the vinyl chloride resin paste composition to inoculation emulsion polymerization in a polymerization reactor equipped with a reflux condenser to produce a vinyl chloride resin, spray drying the vinyl chloride resin to obtain vinyl chloride resin paste, where an anionic surfactant of the vinyl chloride resin paste composition is added in the first step before adding vinyl chloride monomer in the preparation of the vinyl chloride resin to the polymerization reactor, and a cationic surfactant of the vinyl chloride resin paste composition is added in the first step before adding vinyl chloride monomer to the polymerization reactor, when a polymerization conversion rate is = 30% during production of the vinyl chloride resin.
机译:氯乙烯树脂糊剂组合物包括(以重量份计):阴离子表面活性剂(0.2-2),阳离子表面活性剂(0.005-0.05),聚合引发剂(0.01-1)和接种物(1-10),基于氯乙烯单体(100)。还包括用于生产具有改进的聚合热控制的氯乙烯树脂糊的独立权利要求,包括使氯乙烯树脂糊组合物在配备有回流冷凝器的聚合反应器中进行乳液聚合接种以生产氯乙烯树脂,将乙烯喷雾干燥。氯乙烯树脂制得氯乙烯树脂糊剂,其中在第一步中加入氯乙烯树脂糊剂组合物的阴离子表面活性剂,然后将制备氯乙烯树脂的氯乙烯单体加到聚合反应器中,然后在其中加入阳离子表面活性剂。当在氯乙烯树脂的生产过程中聚合转化率= 30%时,在将氯乙烯单体加入聚合反应器之前的第一步中,加入氯乙烯树脂糊剂组合物。

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