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Bis(trifluoromethanesulfonyl)ethyl-bearing compound and acid catalyst, and method for preparing same

机译:含双(三氟甲磺酰基)乙基的化合物和酸催化剂及其制备方法

摘要

[Problem] To provide an acid catalyst which can reduce the quantity of waste in an organic synthesis reaction and which does not corrode a reactor and is nontoxic. [Solution] The problem is resolved by using a bis(trifluoromethanesulfonyl)ethyl-bearing phenolic compound. The compound can be utilized as a catalyst in various organic chemical reactions, particularly in organic synthesis reactions such as Diels-Alder reaction, Friedel-Crafts reaction, Michael addition reaction and esterification reaction. This acid catalyst exhibits higher activity in comparison to a conventional Lewis acid, and therefore need not be used in a stoichiometric amount. Namely, the acid catalyst enables, even when used in an extremely small amount, a desired organic reaction to proceed. Further, the acid catalyst is soluble in various solvents and therefore permits homogeneous reaction, while the acid catalyst can be easily and simply separated from a desired reaction product after the completion of reaction. The acid catalyst is further characterized by making it possible to carry out a reaction at a relatively low temperature near ordinary temperature, thus being highly useful also in an industrial manufacturing process.
机译:[问题]提供一种可以减少有机合成反应中的废物量并且不腐蚀反应器并且无毒的酸催化剂。 [解决方案]该问题通过使用带有双(三氟甲磺酰基)乙基的酚类化合物解决。该化合物可以在各种有机化学反应中用作催化剂,特别是在有机合成反应中,例如Diels-Alder反应,Friedel-Crafts反应,Michael加成反应和酯化反应中。与常规的路易斯酸相比,该酸催化剂表现出更高的活性,因此不需要以化学计量的量使用。即,即使以极少量使用,酸催化剂也能够进行期望的有机反应。此外,酸催化剂可溶于各种溶剂中,因此允许均相反应,而在反应完成后,酸催化剂可容易且简单地与所需反应产物分离。酸催化剂的特征还在于可以在接近常温的较低温度下进行反应,因此在工业制造过程中也非常有用。

著录项

  • 公开/公告号GB2500551A

    专利类型

  • 公开/公告日2013-09-25

    原文格式PDF

  • 申请/专利权人 CENTRAL GLASS COMPANY LIMITED;

    申请/专利号GB20130012783

  • 发明设计人 HIKARU YANAI;TAKEO TAGUCHI;

    申请日2011-12-08

  • 分类号C07C317/18;B01J31/02;C07B61/00;C07C67/08;C07C69/78;C07C315/04;C07C317/28;C07C317/46;C07F7/18;

  • 国家 GB

  • 入库时间 2022-08-21 16:20:16

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