首页> 外国专利> LANTHANUM HEXABORIDE SINTERED BODY, PRODUCTION METHOD THEREOF, LANTHANUM HEXABORIDE FILM AND ORGANIC SEMICONDUCTOR DEVICE

LANTHANUM HEXABORIDE SINTERED BODY, PRODUCTION METHOD THEREOF, LANTHANUM HEXABORIDE FILM AND ORGANIC SEMICONDUCTOR DEVICE

机译:六硼化镧烧结体,其制备方法,六硼化镧膜和有机半导体装置

摘要

PROBLEM TO BE SOLVED: To provide a lanthanum hexaboride sintered body having a high relative density with which a lanthanum hexaboride film having a low work function can be obtained and a production method thereof.;SOLUTION: The sintered body is a lanthanum hexaboride sintered body in which lanthanum hexaboride and a rare earth metal boride with one or more electrons in 4f-orbitals are dissolved. Its oxygen element content is 1.0 mass% or less. Its carbon element content is 0.1 mass% or less. Its relative density is 88% or more. Its lattice constant is 4.1445Å or more and 4.1518Å or less. The production method for the lanthanum hexaboride sintered body comprises: a step (a) of treating a powder of lanthanum hexaboride and a powder of a rare earth metal boride with one or more electrons in 4f-orbitals with acid and obtaining a purified lanthanum hexaboride powder and a purified rare earth metal boride powder; and a step (b) of sintering a mixed powder of the purified lanthanum hexaboride powder and the purified rare earth metal boride powder obtained at the step (a) in one atmosphere selected from a reduction atmosphere and an inert gas atmosphere at 1700°C or higher under 10 MPa or higher.;COPYRIGHT: (C)2014,JPO&INPIT
机译:解决的问题:提供一种高相对密度的六硼化镧烧结体,并由此获得具有低功函的六硼化镧膜及其生产方法。解决方案:该烧结体是一种六硼化镧烧结体。将六硼化镧和具有一个或多个电子的4f轨道中的稀土金属硼化物溶解。其氧元素含量为1.0质量%以下。其碳元素含量为0.1质量%以下。其相对密度为88%以上。其晶格常数为4.1445Å以上且4.1518Å以下。六硼化镧烧结体的制造方法包括:步骤(a):用酸处理六硼化镧粉末和具有一个或多个电子的稀土金属硼化物粉末在4f-轨道中用酸处理,得到纯化的六硼化镧粉末。以及纯化的稀土金属硼化物粉末;步骤(b)是在选自还原气氛和惰性气体气氛中的一种气氛中于1700℃或以下的温度下烧结由步骤(a)获得的纯化的六硼化镧镧粉末和纯化的稀土金属硼化物粉末的混合粉末。在10 MPa或更高压力下更高。;版权所有:(C)2014,JPO&INPIT

著录项

  • 公开/公告号JP2014019584A

    专利类型

  • 公开/公告日2014-02-03

    原文格式PDF

  • 申请/专利权人 SUMITOMO OSAKA CEMENT CO LTD;

    申请/专利号JP20120156358

  • 发明设计人 TAKAHASHI KENTARO;

    申请日2012-07-12

  • 分类号C04B35/50;C01B35/04;C23C14/34;C23C14/06;

  • 国家 JP

  • 入库时间 2022-08-21 16:16:23

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