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Solution-based method for producing a graphene nanoribbons

机译:基于溶液的石墨烯纳米带的制备方法

摘要

Embodiments of the present invention provide methods of preparing functionalized graphene nanoribbons by (1) exposing a plurality of carbon nanotubes to an alkali metal source in the presence of an aprotic solvent, wherein the exposing opens the carbon nanotubes; and (2) exposing the opened carbon nanotubes to an electrophile to form functionalized graphene nanoribbons. Such methods may also include a step of exposing the opened carbon nanotubes to a protic solvent in order to quench any reactive species on the opened carbon nanotubes. Further embodiments of the present invention pertain to graphene nanoribbons formed by the methods of the present invention. Additional embodiments of the present invention pertain to nanocomposites and fibers containing the aforementioned graphene nanoribbons.
机译:本发明的实施方案提供了通过以下方法制备官能化的石墨烯纳米带的方法:(1)在质子惰性溶剂存在下将多个碳纳米管暴露于碱金属源,其中所述暴露打开碳纳米管; (2)将打开的碳纳米管暴露于亲电试剂中以形成官能化的石墨烯纳米带。这样的方法还可以包括将打开的碳纳米管暴露于质子溶剂中以淬灭打开的碳纳米管上的任何反应性物种的步骤。本发明的其他实施方案涉及通过本发明的方法形成的石墨烯纳米带。本发明的另外的实施方案涉及包含上述石墨烯纳米带的纳米复合材料和纤维。

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