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Method for the preparation of alkyl aryl sulfonic acids and alkyl aryl sulfonates

机译:烷基芳基磺酸和烷基芳基磺酸盐的制备方法

摘要

A process for preparing an alkyl aryl sulfonic acid, in contact with the gaseous sulfonating agent: (a) alkyl aromatic hydrocarbons first liquid reaction product comprising (i) an alkyl aryl sulfonic acid and (ii the second liquid reaction product purification and gas flow and (c) purifying gaseous effluent stream; process of separating from the gaseous effluent stream (b) a first liquid reaction product; generating a) gaseous discharge flow process to obtain a; then was recycled to the first liquid reaction product produced after the separation step (b) (d) a second liquid reaction product to produce a third liquid reaction product containing alkyl aryl sulfonate is obtained by the method comprising the alkyl aromatic hydrocarbon is contacted with an olefin and an aromatic hydrocarbon alkylation conditions, and is obtained by dehydrogenation of the Fischer-Tropsch derived paraffinic feedstock is the olefin method.
机译:与气态磺化剂接触的烷基芳基磺酸的制备方法:(a)烷基芳烃第一液体反应产物,其包含(i)烷基芳基磺酸和(ii)第二液体反应产物的纯化和气流以及(c)净化气态流出物流;从气态流出物流中分离(b)第一液体反应产物的过程;产生a)气态排放流过程以获得a的过程;然后再循环至分离步骤(b)之后产生的第一液体反应产物(d)中,通过使包含烷基芳烃的方法与第二方法反应获得的第二液体反应产物,该第三液体反应产物含有烷基芳基磺酸烷基酯。烯烃和芳烃的烷基化条件,以及通过费-托衍生的链烷烃原料的脱氢得到的是烯烃方法。

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