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A PROCESS FOR OBTAINING RECOVERABLE DEFORMATIONS IN SHAPE MEMORY POLYMERS (SMP)

机译:在形状记忆聚合物(SMP)中获得可恢复形变的过程

摘要

The present invention relates to the large, elastic recoverable (thermo-mechanically induced) deformations of a hollow or solid, epoxy or other shape memory polymer (SMP) based material specimens realized through selective zonal heating using non-contact type of heating techniques. These deformations may be in axial, bending or shear mode. This invention is based on the differential modulus created by selective zonal heating followed by cooling. These heat cool cycles may further be broken down into heating selective zones (to varying temperatures) of the SMP specimen to a temperature above the transition temperature, (Tg or Tm) (2) elastically deforming by mechanical loading, (3) cooling under load, (4) completely unloading in cold state and (5) again re-heating to a temperature above transition temperature. The selective heating is done in such a way so as to effect large elastic deformations in the specimen. The differential modulus between the zones at a higher temperature and those zones at a lower temperature results in large elastic deformations. These are almost completely recoverable in both quasi-static and cyclic types of thermo mechanical loading for all modes of deformation.
机译:本发明涉及基于中空或固体,环氧树脂或其他形状记忆聚合物(SMP)的材料样品的大的弹性可恢复(热机械诱导)变形,该材料样品是通过使用非接触式加热技术的选择性区域加热来实现的。这些变形可以是轴向,弯曲或剪切模式。本发明基于通过选择性地带加热然后冷却而产生的微分模量。这些热冷却循环可进一步细分为SMP样品的加热选择区域(以变化的温度)至高于转变温度(Tg或Tm)的温度;(2)通过机械载荷发生弹性变形;(3)在载荷下冷却,(4)在冷态下完全卸载,(5)再次重新加热到高于转变温度的温度。选择性加热以在样品中引起大的弹性变形的方式进行。较高温度区域与较低温度区域之间的差异模量导致较大的弹性变形。对于所有变形模式,在准静态和循环类型的热机械载荷中,这些几乎都可以完全恢复。

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