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Use of a binder based on biopolymers in roadside and cilvil engineering applications
Use of a binder based on biopolymers in roadside and cilvil engineering applications
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机译:基于生物聚合物的粘合剂在路边和土木工程应用中的用途
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摘要
Use of a binder comprising at least a resin based on polymerized hydroxyacid derivatives, as a non-bituminuous binder in coating, marking products and sealing products, is claimed, where the resin is e.g. (a) organic resins derived from oil or grease of natural origin comprising monoglycerides and/or diglycerides, esterified by a polyhydroxy acid compound (A). Use of a binder comprising at least a resin based on polymerized hydroxyacid derivatives, as a non-bituminuous binder in coating, marking products and sealing products, is claimed, where the resin is: (a) organic resins derived from oil or grease of natural origin comprising monoglycerides and/or diglycerides, esterified by a polyhydroxy acid compound of formula (H 2C(O-COR 1)-CH(O-R 2)-CH 2(O-(hydroxy-acid) n-C=O-X-OH)) (A); (b) organic resins corresponding to esters of polylactic acid and polyol such as glycerol, 1,2 and 1,3-propanediol and/or mono or polyhydroxylated polyacid such as malic acid, citric acid, tartaric acid or their esters, preferably glycerol or citric acid; and/or (c) organic resins based on polylactic acid or its derivative such as corresponding esters. R 16-32C aliphatic hydrocarbon chain optionally substituted by alkyl or hydroxyl groups; R 2H or -COR 4; R 4R 1or polyhydroxy acid ester; X : -CH 2or -CHR; R : 1-5C alkyl and comprising 0-5 hydroxyl functions; and n (number of hydroxy acid units) : 3-2000. Where the poly(hydroxy acid) group corresponding to [hydroxy acid] n-CO-X-OH is a linear or branched chain, obtained by condensation of hydroxy acid monomers. Independent claims are included for: (1) a material for producing layer and/or construction coating, comprising an aggregate and the binder; (2) a layer or construction coating obtained in situ by applying a mixture of binder and aggregate on pavement or by spreading on the pavement of the binder before or after spreading the aggregate; (3) a road marking product comprising the binder (10-50%), pigments (1-40%) and fillers (20-60%); and (4) a sealing product such as a membrane and/or geomembrane comprising a fabric impregnated with a binder medium comprising the binder and limestone type filler.
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机译:要求使用至少包含基于聚合羟基酸衍生物的树脂的粘合剂作为非沥青粘合剂在涂料,标记产品和密封产品中的用途,其中该树脂例如为丙烯酸。 (a)衍生自天然来源的油或油脂的有机树脂,其包含被多羟基酸化合物(A)酯化的甘油单酯和/或甘油二酯。要求包含至少一种基于聚合羟基酸衍生物的树脂的粘合剂作为非沥青粘合剂在涂料,标记产品和密封产品中的用途,其中该树脂为:(a)衍生自天然油脂的有机树脂由式(H 2C(O-COR 1)-CH(OR 2)-CH 2(O-(羟基酸)nC = OX-OH)的多羟基酸化合物酯化的单酸甘油酯和/或二酸甘油酯的原料(一种); (b)对应于聚乳酸和多元醇的酯的有机树脂,例如甘油,1,2和1,3-丙二醇和/或单或多羟基化的多元酸,例如苹果酸,柠檬酸,酒石酸或它们的酯,优选甘油或柠檬酸; (c)基于聚乳酸或其衍生物的有机树脂,例如相应的酯。 R 16-32C任选被烷基或羟基取代的脂族烃链; R 2H或-COR 4; R 4R 1或聚羟基酸酯; X:-CH 2或-CHR; R:1-5C烷基,且具有0-5个羟基官能团; n(羟基酸单元数):3-2000。其中对应于[羟基酸] n-CO-X-OH的聚(羟基酸)基团是通过羟基酸单体的缩合获得的直链或支链。包括以下独立权利要求:(1)一种用于生产层和/或建筑涂料的材料,其包括骨料和粘合剂; (2)通过在铺展骨料之前或之后在路面上施加粘合剂和骨料的混合物或通过在铺展的粘合剂上铺展而在现场获得的层或建筑涂料; (3)一种道路标志产品,包括粘合剂(10-50%),颜料(1-40%)和填料(20-60%); (4)一种密封产品,例如膜和/或土工膜,其包含浸渍有包含粘合剂和石灰石型填料的粘合剂介质的织物。
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