首页> 外国专利> METHOD FOR PRODUCING SULFONYL AMIDE COMPOUND CONTAINING FLUORINATED ALIPHATIC GROUP AND METHOD FOR PRODUCING ANIONIC HYDROPHILIC GROUP-CONTAINING SURFACTANT

METHOD FOR PRODUCING SULFONYL AMIDE COMPOUND CONTAINING FLUORINATED ALIPHATIC GROUP AND METHOD FOR PRODUCING ANIONIC HYDROPHILIC GROUP-CONTAINING SURFACTANT

机译:含氟烷基的酰胺基化合物的制备方法及阴离子型含亲水基的表面活性剂的制备方法

摘要

The objective of the present invention is to provide a method for producing, at a high yield, a sulfonyl amide compound containing a fluorinated aliphatic group, the method comprising: a first step of adding a ketone compound (a1) having 5 to 10 carbon atoms and a diamine compound (a2) to an organic solvent (a3) such that the ratio of carbonyl groups (a1-1) in the ketone compound (a1) and amino groups (a2-1) in the diamine compound (a2) is in a range of 0.3 to 0.95 in [(a1-1)/(a2-1)] molar ratio, and reacting the ketone compound (a1) and the diamine compound (a2) in the organic solvent (a3) to obtain a compound (A) that contains an amino group and a ketimine group; a second step of reacting the compound (A) with a sulfonyl chloride compound (B) containing a fluorinated aliphatic group to obtain a fluorinated aliphatic group-containing compound (C) that has a ketimine group; and a third step of hydrolyzing the ketimine group in the compound (C) to generate an amino group in the compound (C).
机译:本发明的目的是提供一种以高收率生产含有氟化脂肪族基团的磺酰胺化合物的方法,该方法包括:第一步,添加具有5至10个碳原子的酮化合物(a1)。将二胺化合物(a2)加入有机溶剂(a3)中,使酮化合物(a1)中的羰基(a1-1)与二胺化合物(a2)中的氨基(a2-1)之比为[(a1-1)/(a2-1)]的摩尔比为0.3〜0.95的范围,使酮化合物(a1)与二胺化合物(a2)在有机溶剂(a3)中反应,得到化合物( A)含有氨基和酮亚胺基;第二步骤是使化合物(A)与含有氟代脂肪族基团的磺酰氯化合物(B)反应,得到具有酮亚胺基的含氟代脂肪族基团的化合物(C)。第三步是水解化合物(C)中的酮亚胺基以在化合物(C)中产生氨基。

著录项

  • 公开/公告号WO2013172412A1

    专利类型

  • 公开/公告日2013-11-21

    原文格式PDF

  • 申请/专利权人 DIC CORPORATION;

    申请/专利号WO2013JP63657

  • 申请日2013-05-16

  • 分类号C07C303/40;C07C311/09;C07B51/00;C07C249/02;C07C251/08;C07C303/38;

  • 国家 WO

  • 入库时间 2022-08-21 15:53:18

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