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Use of a multiple range indicator for determining the dose of UV-radiation in at least two wavelength-ranges and method for the determination of a dose of UV radiation

机译:使用多范围指示器来确定至少两个波长范围内的紫外线辐射的剂量以及确定紫外线辐射剂量的方法

摘要

A multirange indicator comprises first indicator system, which encompasses first indicator dye and photolatent Lewis acid or photolatent Lewis base, and which, on exposure of the photolatent Lewis acid or base to electromagnetic radiation, is capable of liberating Lewis acid or base and of changing light absorption of first indicator dye; and second indicator system, which encompasses second indicator dye, and which is capable of changing light absorption of second indicator dye which is a triphenylmethane dye. Multirange indicator comprises first indicator system, which encompasses first indicator dye and photolatent Lewis acid or photolatent Lewis base, and which, on exposure of the photolatent Lewis acid or, respectively, photolatent Lewis base to electromagnetic radiation with wavelengths from first radiation wavelength range, is capable of liberating Lewis acid or base and of changing light absorption of the first indicator dye during a first reaction of the first indicator dye with the liberated Lewis acid or base; and second indicator system, which encompasses second indicator dye, and which is capable of changing light absorption of the second indicator dye in second reaction on exposure to electromagnetic radiation with wavelengths from second radiation wavelength range, where the second indicator dye is triphenylmethane dye. A central carbon atom of the methane group has bonding to a structural unit comprising halogens, pseudohalogens, chalcogens, sulfates, and optionally substituted tosylates, and = 1 of the C6 rings of the phenyl groups has, in ortho- or para-position with respect to the bond to the central methyl carbon atom, an electron-withdrawing substituent with +M effect, and/or has, in meta-position with respect to the bond to the central methyl carbon atom, an electron-donating substituent with +M effect. Independent claims are included for: (1) a method of producing a dose measurement coating for the measurement of UV radiation and/or of electron-beam radiation comprising employing the multirange indicator; (2) a dose-measurement coating material for the measurement of UV radiation and/or electron-beam radiation; (3) a method for producing a flat dose-measurement element for the measurement of UV radiation and/or electron-beam radiation; (4) a flat dose-measurement element for the measurement of UV radiation and/or electron-beam radiation; and (5) a method for determination of the dose of electromagnetic radiation incident on a test specimen comprising providing portion of the surface of the test specimen with the multirange indicator, exposing the test specimen to electromagnetic radiation, recording change in the light absorption of first and second indicator dyes, and determining and using calibration values, the dose of the incident electromagnetic radiation.
机译:多范围指示剂包括第一指示剂系统,其包含第一指示剂染料和光潜性路易斯酸或光潜性路易斯碱,并且在光潜性路易斯酸或碱暴露于电磁辐射下时能够释放路易斯酸或碱并改变光吸收第一指示剂染料;第二指示剂系统,其包含第二指示剂染料,并且能够改变作为三苯甲烷染料的第二指示剂染料的光吸收。多范围指示剂包括第一指示剂体系,其包含第一指示剂染料和光潜性路易斯酸或光潜性路易斯碱,并且在光潜性路易斯酸或光潜性路易斯碱分别暴露于具有来自第一辐射波长范围的波长的电磁辐射时,是在第一指示剂染料与释放的路易斯酸或碱的第一反应期间,能够释放路易斯酸或碱并改变第一指示剂染料的光吸收;第二指示剂系统,其包含第二指示剂染料,并且能够在暴露于具有来自第二辐射波长范围的波长的电磁辐射的第二反应中改变第二指示剂染料的光吸收,其中第二指示剂染料是三苯甲烷染料。甲烷基团的中心碳原子键合至包含卤素,假卤素,硫属元素化合物,硫酸盐和任选取代的甲苯磺酸酯的结构单元,并且≥= 1的苯基C6环在邻位或对位具有相对于与中央甲基碳原子的键而言,具有+ M效应的吸电子取代基,和/或相对于与中央甲基碳原子的键而言具有间位具有+ M的供电子性取代基影响。包括以下独立权利要求:(1)一种生产用于测量UV辐射和/或电子束辐射的剂量测量涂层的方法,该方法包括使用多量程指示器; (2)用于测量UV辐射和/或电子束辐射的剂量测量涂层材料; (3)一种制造用于测量UV辐射和/或电子束辐射的扁平剂量测量元件的方法; (4)用于测量UV辐射和/或电子束辐射的扁平剂量测量元件; (5)一种用于确定入射到试样上的电磁辐射的剂量的方法,该方法包括:在试样表面的一部分上提供多量程指示器,使试样暴露于电磁辐射下,记录第一试样的光吸收变化。第二指示剂染料,并确定并使用校准值确定入射电磁辐射的剂量。

著录项

  • 公开/公告号EP2172752B1

    专利类型

  • 公开/公告日2014-06-04

    原文格式PDF

  • 申请/专利权人 TESA SE;

    申请/专利号EP20090170409

  • 申请日2009-09-16

  • 分类号G01N31/22;G01J1/50;G01K3/04;G01T1/04;G03C1/685;G03F7/105;G03C1/73;

  • 国家 EP

  • 入库时间 2022-08-21 15:50:52

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