首页> 外国专利> MULTI COMPONENT MIXTURE OF MAGNESIUMCOHOLATES, MAGNESIUMHALIDES AND ALCOHOL, PROCESSES TO MAKE THEM AND THEIR USE IN PROCESSES TO MAKE OLEFIN POLYMERIZATION CATALYST

MULTI COMPONENT MIXTURE OF MAGNESIUMCOHOLATES, MAGNESIUMHALIDES AND ALCOHOL, PROCESSES TO MAKE THEM AND THEIR USE IN PROCESSES TO MAKE OLEFIN POLYMERIZATION CATALYST

机译:碳酸镁,镁盐和醇的多组分混合物,其制备方法及其在制备烯烃聚合催化剂的过程中的用途

摘要

The present invention provides a solid organomagnesium precursor having formula {Mg(OR')X}.a{MgX2}.b{Mg(OR')2}.c{R'OH}, wherein R' is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5 : 0.01 - 0.5 : 0.01 - 5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. The organomagnesium precursor is prepared as follows: At 0°C, magnesium in diethyl ether is reacted with the organohalide. After all magnesium has reacted, the calculated amount of alcohol was added and after the completion of addition, the ether was evaporated and a solid compound obtained.
机译:本发明提供了具有式{Mg(OR')X} .a {MgX 2 }。b {Mg(OR') 2 }。c的固体有机镁前体。 {R'OH},其中R'选自烃基,X选自卤素基团,并且a:b:c的范围为0.01-0.5:0.01-0.5:0.01-5,并且其制备方法同样,所述方法包括使镁源与溶剂化剂,有机卤化物和醇接触以获得固体有机镁前体。本发明还提供了使用有机镁前体制备催化剂体系的方法及其在烯烃聚合中的用途。有机镁前体的制备如下:在0°C下,乙醚中的镁与有机卤化物反应。在所有镁反应之后,添加计算量的醇,并且在添加完成之后,蒸发醚,获得固体化合物。

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