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POLYCARBONATE-POLY(ETHER-ESTER) COPOLYMER COMPOSITION, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM

机译:聚碳酸酯-酯(酯)共聚物的组成,制造方法及其制品

摘要

A composition comprising: a polycarbonate comprising units derived from a bisphenol cyclohexylidene of the formula: wherein Rc1 and Rd1 are each independently C1-12 alkyl, Rc2 and Rd2 are each independently hydrogen or C1-12 alkyl, Rg is C1-12 alkyl or halogen, and t is 0 to 10; and a poly(ether-ester) copolymer comprising 40 to 60 wt % of polyester hard block units derived from a C6-C24 aromatic dicarboxylic acid or a C6-C24 alicyclic dicarboxylic acid and at least one glycol component, wherein when the C6-C24 aromatic dicarboxylic acid comprises terephthalic acid, isophthalic acid groups are present in an amount from 0 to 30 mole %, based on the total moles of isophthalic acid groups and terephthalic acid groups in the hard block units, and 40 to 60 wt % of polyether soft block units derived from poly(oxytetramethylene) glycol, wherein the molecular weight of the poly(oxytetramethylene) glycol groups is 300 to 1800 Daltons.
机译:一种组合物,包括:聚碳酸酯,其包含衍生自下式的双酚环己叉基的单元:其中Rc1和Rd1各自独立地为C1-12烷基,Rc2和Rd2各自独立地为氢或C1-12烷基,Rg为C1-12烷基或卤素,并且t为0至10;以及包含40至60重量%的衍生自C6-C24芳族二羧酸或C6-C24脂环族二羧酸的聚酯硬嵌段单元和至少一种二醇组分的聚(醚-酯)共聚物,其中当C6-C24芳族二羧酸包括对苯二甲酸,基于硬嵌段单元中的间苯二甲酸基团和对苯二甲酸基团的总摩尔数,间苯二甲酸基团的存在量为0至30摩尔%,以及40至60重量%的聚醚软基衍生自聚(氧化四亚甲基)二醇的嵌段单元,其中聚(氧化四亚甲基)二醇基的分子量为300至1800道尔顿。

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