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SYNTHESIS OF BIOBASED TEREPHTHALIC ACIDS AND ISOPHTHALIC ACIDS

机译：生物基对苯二甲酸和间苯二甲酸的合成

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摘要

Methods for producing bio-terephthalic acid and bio-isophthalic acid. Methods comprise a cycloaddition reaction to produce bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic from bio-isoprene and bio-acrylic acid. An aromatization reaction produces bio-para-toluic acid and bio-meta-toluic acid from the bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic. An oxidation reaction produces the bio-terephthalic acid and iso-phthalic acid from the bio-para-toluic acid and bio-meta-toluic acid.

机译：生产生物对苯二甲酸和生物间苯二甲酸的方法。方法包括环加成反应以从生物异戊二烯和生物丙烯酸生产生物-4-甲基-3-环己烯-1-羧酸和生物-3-甲基-3-环己烯-1-羧酸。芳构化反应从生物-4-甲基-3-环己烯-1-羧酸产生生物对-甲苯甲酸和生物间位-甲苯甲酸， -3-甲基-3-环己烯-1-羧酸。氧化反应从生物对苯甲酸和生物间甲苯甲酸生产生物对苯二甲酸和间苯二甲酸。 展开▼

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公开/公告号WO2014144843A1

专利类型

公开/公告日2014-09-18

原文格式PDF

申请/专利权人 BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY;
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申请/专利号WO2014US29422

发明设计人 FROST JOHN W.;
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申请日2014-03-14

分类号C08G63/183;C07C51/265;C07C51/353;C07C51/377;

国家 WO

入库时间 2022-08-21 15:47:19

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