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The method of aromatic compounds production using tungsten oxide titania catalyst for hydrodeoxygenation of Guaiacol

机译:氧化钨二氧化钛催化剂对愈创木酚加氢脱氧制备芳族化合物的方法

摘要

The invention guaiacol (Guaiacol) for the reaction of lignin can cheomtal oxygen conversion material containing the is tungsten oxide on the titania supported catalyst. More specifically, the reduction of the tungsten oxide supported on the use of molybdenum in a conventional catalyst with no oxygen can not cheomtal reported titania-oxygen reaction process will be cheomtal about through a change in the co-catalyst and sulfiding. Tungsten titania catalyst prepared by the present invention can be converted to aromatic chemicals such as phenol and guaiacol. In particular, the catalyst was anatase to rutile is higher than the yield of phenol, in the case of cobalt showed a higher phenol yield. Nickel-tungsten or cobalt titania supported catalyst of the present invention as described above by changing the structure of titania and a co-catalyst in the manufacturing process improves the hydrogenated deoxygenation reaction. In particular showed better performance than before after conversion to phenol sulfide treatment. ;
机译:用于木质素反应的本发明的愈创木酚(Guaiacol)可以在二氧化钛负载的催化剂上化学合成包含氧化钨的氧的交换材料。更具体地说,在无氧的常规催化剂中使用钼负载的氧化钨的还原不能使所报道的二氧化钛-氧反应过程发生化学反应,这是通过改变助催化剂和硫化来实现的。通过本发明制备的钨二氧化钛催化剂可以转化为芳族化学品,例如苯酚和愈创木酚。特别地,在钴显示更高的苯酚收率的情况下,催化剂的锐钛矿到金红石的产率高于苯酚的收率。如上所述,通过在制造过程中改变二氧化钛和助催化剂的结构,本发明的镍-钨或钴的二氧化钛负载的催化剂改善了氢化脱氧反应。特别是表现出比转化为苯酚硫化物处理之前更好的性能。 ;

著录项

  • 公开/公告号KR101336981B1

    专利类型

  • 公开/公告日2013-12-04

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20110107191

  • 发明设计人 홍윤기;이관영;엄희준;정상호;

    申请日2011-10-19

  • 分类号C07C1/20;B01J23/30;C07C15/04;C07C39/04;

  • 国家 KR

  • 入库时间 2022-08-21 15:44:08

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