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CATALYSTS FOR THE PRODUCTION OF HIGHER CALORIFIC SYNTHETIC NATURAL GAS AND THE PREPARATION METHOD THEREOF

机译:生产高热量合成天然气的催化剂及其制备方法

摘要

The present invention relates to a catalyst for producing synthetic natural gas (SNG) in which methanation reaction and fischer-tropsch synthesis are progressed at the same time, and a manufacturing method thereof and, more specifically, to a catalyst for producing a high calorific methane gas comprising: 30-90 parts by weight of a metal support; and a catalyst activating ingredients including 10-70 parts by weight of nickel and 1-10 parts by weight of one metal element selected from Fe, Co, Zr, Ce and Ga. The manufacturing method for the catalyst comprises: a catalyst active ingredient producing step; and an impregnating step of impregnating the catalyst activating ingredients into the metal support. The present invention increases the yield of carbon (C) by performing the process in conditions in which the H_2/CO ratio of syngas supplied to methanation reaction is lower than 3.0 since methanation reaction and fischer-tropsh synthesis occur at the same time by using the catalyst in a manufacturing method for synthetic natural gas (SNG), exhibits excellent reproducibility by allowing high calorific synthetic natural gas to be produced and provides the catalyst for synthesizing high calorific methane through a simple manufacturing process.
机译:本发明涉及同时进行甲烷化反应和费-托合成的合成天然气(SNG)生产用催化剂及其制造方法,更具体地,涉及高热甲烷的生产用催化剂。气体,其包含:30-90重量份的金属载体;所述催化剂的制备方法包括:催化剂活性成分的制备;以及催化剂活性成分,其包含10-70重量份的镍和1-10重量份的选自Fe,Co,Zr,Ce和Ga的一种金属元素。步;浸渍步骤是将催化剂活化成分浸渍到金属载体中。通过使用甲烷化反应同时进行甲烷化反应和费-托合成,在供给至甲烷化反应的合成气的H_2 / CO比低于3.0的条件下进行该工艺,从而提高了碳(C)的收率。在用于合成天然气(SNG)的制造方法中的催化剂,通过允许生产高热量的合成天然气而表现出优异的可再现性,并且通过简单的制造过程提供了用于合成高热量的甲烷的催化剂。

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