首页> 外国专利> POLYMERS MADE WITH METALLOCENE CATALYSTS, FOR USE IN ROTOMOLDING AND INJECTION MOLDING PRODUCTS

POLYMERS MADE WITH METALLOCENE CATALYSTS, FOR USE IN ROTOMOLDING AND INJECTION MOLDING PRODUCTS

机译:用茂金属催化剂制成的聚合物,用于滚塑和注射成型产品

摘要

Ethylene alpha-olefin copolymers formed by contacting at least one supported metallocene catalyst, ethylene, and an alpha-olefin in a gas phase reactor are disclosed. In some embodiments, the polymer may have: a density of between 0.890 and 0.970 g/cc; a melt index of between 0.7 and 200 dg/min; a melt index ratio of less than 30; an ESCR value of greater than 1000 hours; and a 1% secant modulus of greater than 75,000 psi. In other embodiments, the polymer may have: a density of between 0.930 g/cc and 0.970 g/cc; a melt index of between 10 dg/min and 200 dg/min; a melt index ratio of between 10 and 25; a part weight of greater than 3 g and a part length of greater than 38 cm in a spiral flow test, and; a zero shear viscosity of less than 150 Pa·s. Processes to produce these polymers are also disclosed.
机译:公开了通过在气相反应器中使至少一种负载的茂金属催化剂,乙烯和α-烯烃接触而形成的乙烯α-烯烃共聚物。在一些实施方案中,聚合物可具有:0.890至0.970g / cc的密度;和熔体指数在0.7至200dg / min之间;熔体指数比小于30; ESCR值大于1000小时; 1%割线模量大于75,000 psi。在其他实施方案中,聚合物可具有:0.930g / cc至0.970g / cc的密度;和熔体指数在10dg / min至200dg / min之间;熔体指数比在10至25之间;在螺旋流动试验中,零件重量大于3 g,零件长度大于38 cm,并且零剪切粘度小于150 Pa·s。还公开了生产这些聚合物的方法。

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