METAL-ORGANIC FRAMEWORK STRUCTURES OBTAINED FROM CARBENOPHILIC METALS AND METHOD FOR PRODUCING THEM

摘要

1. An organometallic carcass structure containing the general structure M-L-M, where M is a metal of the carcass structure and L is a binding moiety containing heterocyclic carbene. 2. The organometallic carcass structure according to claim 1, wherein the binding residue is metallized before reacting with the metal of the carcass structure. The organometallic framework structure according to claim 1 or 2, wherein the binding residue contains N-heterocyclic carbene. The organometallic framework structure according to claim 1, which includes a covalent organic framework structure (COF), a zeolite imidisole framework structure (ZIF), or an organometallic framework structure (MOF). The organometallic carcass structure of claim 1, wherein the metal of the carcass structure is selected from the group consisting of Li, Na, Rb, Mr, Ca, Sr, Ba, Sc, Ti, Zr, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Pd, Pt, Cu, Au, Zn, Al, Ga, In, Si, Ge, Sn, and Bi. 6. The organometallic framework structure of claim 1, wherein the binding moiety containing heterocyclic carbene is modified with a modifying metal. The organometallic framework structure of claim 6, wherein the modifying metal is selected from the group consisting of Li, Be, Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn , Ga, Ge, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Sn, Te, Ba, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Sm, Eu and Yb. 8. The organometallic carcass structure of claim 6 or 7, wherein the modifying metal extends into the pore of the carcass structure. The organometallic frame structure according to claim 1, which does not contain guest particles. The method for producing an organometallic framework structure according to claim 1, comprising reacting a binding moiety containing heterocyclic carbene and containing a protected binding to