首页> 外国专利> ASSOCIATIVE MONOMER BASED ON OXO-ALCOHOLS, ACRYLIC POLYMER CONTAINING THIS MONOMER, APPLICATION OF THE INDICATED POLYMER AS A THICKENER IN AQUEOUS COMPOSITION, OBTAINED IN THE COMPOSITION

ASSOCIATIVE MONOMER BASED ON OXO-ALCOHOLS, ACRYLIC POLYMER CONTAINING THIS MONOMER, APPLICATION OF THE INDICATED POLYMER AS A THICKENER IN AQUEOUS COMPOSITION, OBTAINED IN THE COMPOSITION

机译:基于氧-醇的缔合单体,包含该单体的丙烯酸聚合物,指示的聚合物作为增稠剂在水性组合物中的应用,在该组合物中获得

摘要

1. The monomer of formula (I) R- (AO) - (BO) -R ', where m and n are integers less than 150, at least one of which is not zero, - A and B denote alkyl groups that differ from each other and containing from 2 to 4 carbon atoms, wherein the AO group is preferably ethylene oxide and the BO group is preferably propylene oxide, - R is a polymerizable unsaturated group, preferably methacrylate, - R 'is characterized in that it consists of at least one group formula (II): CH- (CH) -CH (CH) CH- (CH) -, where p and q are integers, at least one of which is non-zero, where 5 p + q 13, r is an integer equal to 0.2. The monomer according to claim 1, characterized in that n = 0, AO is ethylene oxide and m is from 20 to 40.3. A HASE-type polymer consisting of: a) (meth) acrylic acid, b) at least one (meth) acrylic acid ester, c) at least one monomer of the above formula (I) R- (AO) - (BO) -R ', where m and n are integers less than 150, at least one of which is not zero, - A and B denote alkyl groups that are different from each other and contain from 2 to 4 carbon atoms, while the group AO preferably denotes ethylene oxide and the group BO preferably denotes propylene oxide, - R denotes a polymerizable unsaturated group, pre respectfully methacrylate, R 'is characterized in that it consists of at least one group of formula (II) CH- (CH) -CH (CH) CH- (CH) -, where p and q are integers of at least one of which is not equal to zero, where 5 p + q 13, r is an integer equal to 0.4. The polymer according to claim 3, characterized in that it consists of each of its monomers, expressed, wt.%: A) from 20% to 50%, preferably from 35% to 45%, (meth) acrylic acid�
机译:1.式(I)的单体R-(AO)-(BO)-R',其中m和n是小于150的整数,其中至少一个不为零,-A和B表示不同的烷基彼此之间并含有2-4个碳原子,其中AO基团优选为环氧乙烷,BO基团优选为环氧丙烷,-R为可聚合的不饱和基团,优选为甲基丙烯酸酯,-R'的特征在于它由至少一种基团式(II):CH-(CH)-CH(CH)CH-(CH)-,其中p和q为整数,其中至少一个为非零,其中5 + q <在图13中,r是等于0.2的整数。 2.根据权利要求1所述的单体,其特征在于,n = 0,AO为环氧乙烷,m为20〜40.3。一种HASE型聚合物,由以下组成:a)(甲基)丙烯酸,b)至少一种(甲基)丙烯酸酯,c)至少一种上式(I)的单体R-(AO)-(BO) -R',其中m和n是小于150的整数,其中至少一个不为零,-A和B表示彼此不同并且含有2-4个碳原子的烷基,而基团AO优选代表环氧乙烷,基团BO优选代表环氧丙烷,-R代表可聚合的不饱和基团,优选甲基丙烯酸酯,R'的特征在于,它由至少一个式(II)的基团组成:CH-(CH)-CH( CH)CH-(CH)-,其中p和q是至少其中一个不等于零的整数,其中5 + q <13,r是等于0.4的整数。 4.根据权利要求3的聚合物,其特征在于它由其每种单体组成,以重量%表示:(A)20%至50%,优选35%至45%的(甲基)丙烯酸。

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