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METHOD OF DETERMINING GLUTATHIONE IN STANDARD TEST AQUEOUS SOLUTIONS VIA CYCLIC VOLTAMMETRY ON GRAPHITE ELECTRODE, MODIFIED WITH COLLOIDAL SILVER PARTICLES
METHOD OF DETERMINING GLUTATHIONE IN STANDARD TEST AQUEOUS SOLUTIONS VIA CYCLIC VOLTAMMETRY ON GRAPHITE ELECTRODE, MODIFIED WITH COLLOIDAL SILVER PARTICLES
FIELD: chemistry.;SUBSTANCE: method of determining glutathione involves determination by cyclic voltammetry, wherein there is electrocatalytic oxidation of glutathione on a graphite electrode modified with silver particles. The method according to the invention involves modifying graphite electrodes with colloidal silver particles from a silver sol for 300 s at electrolysis potential of -1.0 V, followed by recording anodic maxima of electrooxidation of glutathione on an anodic curve with potential sweep rate of 100 mV/s on a background of 0.1 M NaOH solution in the potential range from -1.0 V to 1.0 V; concentration of glutathione is determined from the height of anodic maxima of current versus voltage curves in the potential range from 0.30 V to 0.60 V relative a saturated silver chloride electrode by standard addition method.;EFFECT: high sensitivity of the method of determining glutathione.;2 ex, 1 tbl, 2 dwg
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