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BINDER-FREE ADSORBENTS WITH IMPROVED MASS TRANSFER PROPERTIES AND USE THEREOF IN ADSORPTIVE SEPARATION OF PARA-XYLENE
BINDER-FREE ADSORBENTS WITH IMPROVED MASS TRANSFER PROPERTIES AND USE THEREOF IN ADSORPTIVE SEPARATION OF PARA-XYLENE
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机译:改善了传质性能的无粘结剂吸附剂及其在对二甲苯吸附分离中的应用
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摘要
FIELD: chemistry.;SUBSTANCE: described is a method of separating para-xylene from a mixture containing at least one other C8 alkylaromatic hydrocarbon, which includes contacting, under adsorption conditions, the mixture with a binder-free adsorbent containing a first portion of zeolite X and a second portion of zeolite X; wherein said first portion of zeolite X has average crystallite size of 500 nm to 1.5 mcm, and said second portion of zeolite X has average crystallite size smaller than 500 nm or said second portion of zeolite X has average crystallite size greater than 1.8 mcm, wherein the combined first and second portions of zeolite X have average crystallite size smaller than 1.8 mcm, in order to adsorb para-xylene present in the adsorbed phase, preferably compared with at least one other C8 alkylaromatic hydrocarbon present in the non-adsorbed phase; eliminating the non-adsorbed phase from contact with the adsorbent in order to obtain a raffinate stream containing said at least one other C8 alkylaromatic hydrocarbon; and desorbing para-xylene of the adsorbed phase from the adsorbent to obtain an extract stream containing para-xylene; wherein the binder-free adsorbent does not contain amorphous material or contains amorphous in amount of less than 2 wt % in accordance with the defined X-ray diffraction method, wherein the first cycle of said method is less than 34 minutes.;EFFECT: using an adsorbent with improved capacity and mass-transfer, improved efficiency of the method at low temperature, short duration of the adsorptive separation cycle when operating in simulated moving bed mode.;15 cl, 9 dwg, 8 ex
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