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Gold hydroxo anion complex solution and method for producing gold nanoparticle carrier

机译:金羟基阴离子络合物溶液及金纳米颗粒载体的制备方法

摘要

The method for producing a material loaded with gold nanoparticles, includes: impregnating a carrier with an anionic gold-hydroxo complex solution including a transparent solution that has a pH of not lower than 8, does not contain a halide anion, and contains a conjugate base of a weak acid not coordinated to gold and an anionic hydroxo complex of trivalent gold having a square planar molecular geometry whose at least one ligand is OH- and not containing a halide anion as a ligand; removing water; heating; and washing with water. According to the method, in a method for preparing a gold nanoparticle catalyst using a liquid phase method, a gold compound not containing a halide such as chloride is used as a raw material, and the gold compound can be supported efficiently. Furthermore, a gold nanoparticle-loaded catalyst having high activity can be obtained through a simple preparation method.
机译:制备负载有金纳米颗粒的材料的方法,包括:用阴离子金-羟基络合物溶液浸渍载体,所述阴离子金-羟基络合物溶液包括pH值不小于8的透明溶液,不包含卤化物阴离子,并且包含共轭碱。一种不与金配位的弱酸和一种具有方形平面分子几何结构的三价金的阴离子羟基络合物,该分子的至少一个配体是OH-,并且不含有卤化物阴离子作为配体;去除水;加热;并用水冲洗。根据该方法,在使用液相法制备金纳米粒子催化剂的方法中,使用不含诸如氯化物的卤化物的金化合物作为原料,并且可以有效地负载该金化合物。此外,可以通过简单的制备方法获得具有高活性的负载金纳米颗粒的催化剂。

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