9-azanoradamantane N-oxyl compound and method for producing the same, organic molecular oxidation catalyst using 9-azanoradamantane N-oxyl compound, and method for oxidizing alcohols

摘要

In relation to an organic molecular catalyst that oxidizes alcohols, a primary alcohol is selectively oxidized in a polyol substrate having a plurality of alcohols under conditions excellent in environmental harmony. An organic oxidation catalyst for oxidizing alcohols, wherein an oxygen atom is bonded to a nitrogen atom of an azanoradamantane skeleton and has at least one alkyl group at the 1-position and 5-position. INDUSTRIAL APPLICABILITY According to the present invention, there is provided an oxidation catalyst having higher activity than TEMPO, which is an existing oxidation catalyst in a primary alcohol selective oxidation reaction, and being more selective than AZADO and 1-Me-AZADO. In addition, DMN-AZADO according to the present invention can be applied to a primary alcohol selective oxidation reaction that contributes to the shortening of the synthesis of high-value-added organic compounds such as pharmaceuticals, pharmaceutical raw materials, agricultural chemicals, cosmetics, and organic materials. it can.