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Method of manufacturing a hydrogen transfer reaction catalyst and hydrogen transfer reactions containing ruthenium complex

机译:氢转移反应催化剂的制造方法以及含有钌络合物的氢转移反应

摘要

This catalyst for a hydrogen transfer reaction contains a ruthenium complex represented by general formula (1) (in the formula, R1 and R2 are each independently a monovalent hydrocarbon group. Two R1s may bond to each other to form a divalent hydrocarbon group. R1 and R2 may bond to each other to form a divalent hydrocarbon group. R3 and R4 are each independently a hydrogen atom or a monovalent hydrocarbon group. R3 and R4 may bond to each other to form a divalent hydrocarbon group. R5 and R6 are each independently a monovalent linear aliphatic hydrocarbon group or alicyclic hydrocarbon group. X1 is a ligand. The bond between the nitrogen atom and the carbon atom bonding to the nitrogen atom is a double bond or a single bond; in the case where the bond is a single bond, one hydrogen atom may be bonded to the nitrogen atom between the ruthenium atom and R1. m is 0 to 2.).
机译:该氢转移反应用催化剂含有通式(1)表示的钌络合物(式中,R 1和R 2分别独立地为1价的烃基,R 1彼此可以键合而形成2价的烃基。 R 2可以彼此键合形成二价烃基,R 3和R 4各自独立地为氢原子或一价烃基; R 3和R 4彼此键合形成二价烃基; R 5和R 6各自独立地为氢原子。一价直链脂肪族烃基或脂环族烃基,X1为配体,氮原子与碳原子间的键合与氮原子的键为双键或单键;在该键为单键的情况下,钌原子与R 1之间的氮原子上可以键合一个氢原子,m为0〜2。

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