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A method for producing cobalt oxyhydroxide-coated nickel hydroxide.

机译:一种制备氢氧化正钴涂覆的氢氧化镍的方法。

摘要

PROBLEM TO BE SOLVED: To provide a method for inexpensively and efficiently producing cobalt oxyhydroxide-coated nickel hydroxide which is excellent in stability as a battery material without using an expensive oxidizing agent.SOLUTION: Cobalt oxyhydroxide-coated nickel hydroxide including a core material of nickel hydroxide particles represented by general formula: NiCoM(OH)(x is 0.005-0.05; y is 0.005-0.05; and M is one or more of Ca, Mg and Zn) and a cobalt oxyhydroxide coat layer on the surface of the core material is obtained by the method comprising a coating step of continuously producing cobalt hydroxide-coated nickel oxide by supplying nickel hydroxide slurry and a cobalt salt aqueous solution to a reaction tank and also supplying an alkali aqueous solution so as to keep pH 9.5-10.5; and an oxidation step of continuously producing the cobalt oxyhydroxide-coated nickel hydroxide by supplying an alkali aqueous solution and air to slurry of the cobalt hydroxide-coated nickel hydroxide to oxidize it.
机译:解决的问题:提供一种廉价且有效地生产羟基氧化氢氧化钴涂覆的氢氧化镍的方法,该方法在不使用昂贵的氧化剂的情况下作为电池材料具有优异的稳定性。通式:NiCoM(OH)(x为0.005-0.05; y为0.005-0.05; M为Ca,Mg和Zn中的一种或多种)表示的氢氧化物颗粒和在芯材表面上的羟基氧化钴涂层通过包括涂覆步骤的方法获得,该方法包括通过将氢氧化镍浆料和钴盐水溶液供应到反应罐中并且还供应碱水溶液以保持pH 9.5-10.5来连续生产氢氧化钴涂覆的氧化镍的方法。通过将碱性水溶液和空气供给到涂覆有氢氧化钴的氢氧化镍的浆液中以使其连续氧化的氧化步骤;以及通过连续地制造涂覆有氧化氢氧化钴的氢氧化镍的氧化步骤。

著录项

  • 公开/公告号JP5621506B2

    专利类型

  • 公开/公告日2014-11-12

    原文格式PDF

  • 申请/专利权人 住友金属鉱山株式会社;

    申请/专利号JP20100239675

  • 发明设计人 阿部 功;白岡 稔;

    申请日2010-10-26

  • 分类号C01G53;

  • 国家 JP

  • 入库时间 2022-08-21 15:29:05

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