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FREE RADICAL AND CONTROLLED RADICAL POLYMERIZATION PROCESSES USING AZIDE RADICAL INITIATORS
FREE RADICAL AND CONTROLLED RADICAL POLYMERIZATION PROCESSES USING AZIDE RADICAL INITIATORS
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机译:使用叠氮化物自由基引发剂的自由基和可控制的自由基聚合过程
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摘要
A process is described comprising polymerizing at least one unsaturated monomer (e.g., fluorine substituted alkene monomer) in the presence of an azide radical initiator and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one unsaturated monomer to form a polymer. The present disclosure provides a method for the synthesis of polymers with 100% azide chain end functionality, for living/controlled radical polymerization of unsaturated monomers (e.g., fluorine substituted alkene monomers) and for the synthesis of complex polymer architectures, using azide click reactions.
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