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Isotactic polypropylene nucleation

机译:等规聚丙烯成核

摘要

Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
机译:含有丙烯结晶度的低分子量半结晶丙烯-α-烯烃共聚物在结晶聚丙烯和聚丙烯共聚物中用作成核剂。成核共聚物是具有5-75%的结晶度,45℃-105℃的熔点和300-5000g / 10min的MFR的丙烯-α-烯烃共聚物。成核的聚丙烯组合物包含成核量的共混在聚丙烯均聚物或0.01至9重量%的α-烯烃共聚物的基质中的共聚物,其熔点大于110℃。成核的共聚物改善加工时间而几乎没有效果或没有效果。基质的结晶度相关特性。本发明还提供了用成核剂使聚丙烯结晶的方法以及用该组合物形成制品的方法,并且还提供了由该组合物和/或通过该方法形成的制品。

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