Electronically conductive perovskite-based oxide nanoparticles and films for optical sensing applications

摘要

The disclosure relates to a method of detecting a change in a chemical composition by contacting a electronically conducting perovskite-based metal oxide material with a monitored stream, illuminating the electronically conducting perovskite-based metal oxide with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The electronically conducting perovskite-based metal oxide has a perovskite-based crystal structure and an electronic conductivity of at least 10⁻¹ S/cm, where parameters are specified at the gas stream temperature. The electronically conducting perovskite-based metal oxide has an empirical formula A_xB_yO_3-δ, where A is at least a first element at the A-site, B is at least a second element at the B-site, and where 0.8x1.2, 0.8y1.2. Exemplary electronically conducting perovskite-based oxides include but are not limited to La_1-xSr_xCoO₃, La_1-xSr_xMnO₃, LaCrO₃, LaNiO₃, La_1-xSr_xMn_1-yCr_yO₃, SrFeO₃, SrVO₃, La-doped SrTiO₃, Nb-doped SrTiO₃, and SrTiO_3-δ.