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Alkaline earth metal co-precipitated nickel-based catalyst for steam carbon dioxide reforming of natural gas

机译:天然气蒸汽二氧化碳重整用碱土金属共沉淀镍基催化剂

摘要

Disclosed is a catalyst used for steam carbon dioxide reforming of natural gas, wherein an alkaline earth metal alone or an alkaline earth metal and a group 8B metal are supported on a hydrotalcite-like catalyst containing nickel, magnesium and aluminum. The disclosed catalyst is useful as a steam carbon dioxide reforming (SCR) catalyst of natural gas at high temperature and high pressure, while minimizing deactivation of the catalyst due to sintering of the active component nickel and deactivation of the catalyst due to coke generation at the same time. A synthesis gas prepared using the catalyst has a H2/CO molar ratio maintained at 1-2.2. A synthesis gas having a H2/CO molar ratio of 1.8-2.2 may be used as a raw material for Fischer-Tropsch synthesis or methanol synthesis and a synthesis gas having a H2/CO molar ratio of may be used as a raw material for dimethyl ether synthesis.
机译:公开了一种用于天然气的蒸汽二氧化碳重整的催化剂,其中仅碱土金属或碱土金属和8B族金属负载在包含镍,镁和铝的水滑石状催化剂上。所公开的催化剂在高温和高压下用作天然气的蒸汽二氧化碳重整(SCR)催化剂,同时使由于活性组分镍的烧结引起的催化剂失活和由催化剂的焦炭产生引起的催化剂失活最小化。同时。使用该催化剂制备的合成气的H 2 / CO摩尔比保持在1-2.2。具有H 2 / CO摩尔比为1.8-2.2的合成气可以用作费-托合成或甲醇合成的原料以及具有H 2

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