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Method for preparing organic and inorganic hybrid materials based on gelatine and organofunctional poly(siloxanes)

机译:基于明胶和有机官能聚硅氧烷的有机和无机杂化材料的制备方法

摘要

the subject of the invention is a way of organo inorganic hybrid materials based on gelatin and poly (organofunkcyjnych siloksanu00f3w), applicable in packaging industry, measures powu0142okotwu00f3rczych or in the production of biomedical materials.organo inorganic hybrid way receive materials based on gelatin and poly (organofunkcyjnych siloksanu00f3w) is that pork gelatin type a, index bloom and 90 - 300, beef type b, index bloom's 75 - 225 or clammy dissolves in water and heated to temperature in the 40 - 90u00b0c, then added poly (siloxane) with the general formula 1.where r1 is ch3 or alkyl group or aryl group c2h5 c6h5; r2 - functional group containing epoxy group; r3, r4 - equal or different functional group reactive with groups epoksydowymi, i.e. not containing ruchliwego hydrogen atom, such as alkyl groups containing from 1 to 40 atom the carbon; fluoroalkilowe cf2h (cf2) ach2o - or cf3 (cf2) ach2 -; polyether (och2 - ch2) boch3; cyjanianowe,tiocyjanianowe, metakrylowe, amino and k = 0 - 100; m = 1 - 25; n = 0 - 24; l = 0 - 24; x = 2 - 6, y = 2 - 6; z = 2 - 6; and = 0 - 20; b = 0 - 20; previously dissolved in solvent organic by weight gelatin: poly (siloxane) in the (10: 0,25) - (0,25: 10), whereby the reaction is in the range ph 2 - 9, c zasie at least 1 hour.
机译:本发明的主题是一种基于明胶和聚(organofunkcyjnych siloksan u00f3w)的有机无机杂化材料的方法,适用于包装工业,计量,或用于生物医学材料的生产。有机无机杂化方法接收材料基于明胶和聚(organofunkcyjnych siloksan u00f3w)的猪肉明胶类型a,指数布鲁姆和90-300,牛肉类型b,指数布鲁姆75-225或粘稠的溶于水并加热到40- 90 u00b0c ,然后加入通式1的聚(硅氧烷),其中r1是ch3或烷基或芳基c2h5c6h5; r2-含环氧基的官能团; r3,r4-与epoksydowymi基团反应的相同或不同的官能团,即不包含ruchliwego氢原子,例如含1至40个碳原子的烷基; cf2h(cf2)ach2o-或cf3(cf2)ach2-;聚醚(och2-ch2)boch3; cyjanianowe,tiocyjanianowe,metakrylowe,氨基和k = 0-100; m = 1-25; n = 0-24; l = 0-24; x = 2-6,y = 2-6; z = 2-6;和= 0-20; b = 0-20;预先以重量比(10∶0.25)-(0.25∶10)溶于明胶:聚(硅氧烷)的有机溶剂中,由此反应在ph 2-9范围内,至少1小时。

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