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Proton ionic liquid of tebuconazole and propiconazole with dicamba anion and method for producing them

机译:戊唑醇和丙菌唑与麦草畏阴离子的质子离子液体及其制备方法

摘要

the subject invention are proton ion liquids of general formula 1, in which kationem is sprotonowany 1,2,4-triazole originating from tebuconazole and propiconazole, anionem dicamba and their manufacture. liquids are applicable as fungicidal compounds and herbicides.process for the production of ionic liquids is that tebuconazole of the general formula (2) or propiconazole model 3 is subjected to reaction with dikambu0105, mole ratio of tebuconazole or propiconazole to dicamba equal to 1: 0.8 - 1.5 in an alcohol in temperature from 273 to 363k, in time 1 - 48 hours,after which the vaporized solvent and the residue is washed with hexane to remove excess unreacted dicamba and the product dried under reduced pressure at a temperature of 303 to 343k during 1 to 12 hours.
机译:本发明是通式1的质子离子液体,其中kationem是源自戊丁康唑和丙康唑的磺基1,2,4-三唑,麦草畏阴离子及其制备方法。液体可用作杀真菌化合物和除草剂。生产离子液体的方法是使通式(2)的戊唑醇或丙康唑模型3与dikamb u105进行反应,戊唑醇或丙菌唑与麦草畏的摩尔比等于1 :在温度为273至363k的醇中,于1-48小时内在0.8-1.5的乙醇中蒸发,然后用己烷洗涤汽化的溶剂和残留物,以去除过量的未反应麦草畏,并在303的减压下干燥产物在1到12个小时内达到343k。

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