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Bis (ammonium) herbicidal ionic liquids with alkyldiyl-bis (dimethylalkyl ammonium) cations and method for producing them

机译:具有烷基二基双(二甲基烷基铵)阳离子的双(铵)除草离子液体及其制备方法

摘要

the subject of the invention is diamoniowe herbicydowe ionic liquids with cations alkilodiylo - bis (dimetylalkilooamoniowymi) of general formula (1), where r is an alkyl substituent: length of coal from 1 to 16 carbon atoms, and - means anion herbicydowy of general formula (2) or formula (3), and s method for manufacturing them. ionic liquids are used as plant protection products.the solution is also the way they receive, which is that diamoniowy hydroxide is dissolved in methanol, and then undergo reaction inerting in mole ratio of 1:1 solution at a concentration of at least 1% acid, containing a source of anions : (4 - chloro - 2 - metylofenoksy) acetate, or (2,4-dichlorophenoxy) acetate.or (4 - chloro - 2 - metylofenoksy) propionianowego, or 4 - (2,4-dichlorophenoxy) - butanianowego, or (2,4,5 - trichlorofenoksy) acetate, or 4 - (4 - chloro - 2 - metylofenoksy) butanianowego or 3,6 - dichloro - 2 - metoksybenzoesowego.
机译:发明内容本发明的主题是具有通式(1)的烷基烷基二氟-双(二甲烷基烷基氨基季铵盐)阳离子的二铵盐草酸盐离子液体,其中r是烷基取代基:煤的长度为1至16个碳原子,并且-是指通式的阴离子草酸盐(2)或式(3),以及制造它们的方法。离子液体用作植物保护产品。溶液也是它们接收的方式,即将二羟基氢氧化物溶于甲醇中,然后以摩尔比1:1的溶液以至少1%的酸浓度进行反应惰性含有阴离子源:(4-氯-2-甲基苯甲酰氧基)乙酸盐,或(2,4-二氯苯氧基)乙酸酯。或(4-氯-2-甲基苯甲酰氧基)丙酸丙二醇酯,或4-(2,4-二氯苯氧基) -butanianowego,或(2,4,5-trichlorofenoksy)醋酸盐,或4-(4-氯-2-metylofenoksy)butanianowego或3,6-二氯-2-metoksybenzoesowego。

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