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Free Radical Post-Crosslinked Adsorbent and Method of Preparation

机译:自由基后交联吸附剂及其制备方法

摘要

A post-crosslinked adsorbent comprises: monomer units of (a) at least 55 wt% at least one polyvinylaromatic monomer and (b) up to 45 wt% at least one monovinylaromatic monomer; and 0.5-2.5 mmol/g pendent vinyl groups; wherein the dry adsorbent has BET specific surface area in the range of about 650-1000 m2/g, BET average pore diameter 7.2-10 nm, BET porosity 1.29-2.45 mL/g, BJH adsorption micropore volume was less than 20% of total BJH adsorption pore volume, and HK micropore volume was less than 21% of total BJH adsorption pore volume. The invention is also directed to a preparation method for the polymeric adsorbent.
机译:后交联的吸附剂包括:(a)至少55wt%的至少一种聚乙烯基芳族单体和(b)至多45wt%的至少一种单乙烯基芳族单体的单体单元;和0.5-2.5mmol / g的侧基;其中所述干燥吸附剂的BET比表面积为约650-1000m2 / g,BET平均孔径为7.2-10nm,BET孔隙率为1.29-2.45mL / g,BJH吸附微孔体积小于总体积的20% BJH吸附孔体积和HK微孔体积小于总BJH吸附孔体积的21%。本发明还涉及聚合物吸附剂的制备方法。

著录项

  • 公开/公告号EP2138230B1

    专利类型

  • 公开/公告日2015-01-21

    原文格式PDF

  • 申请/专利权人 ROHM & HAAS;

    申请/专利号EP20090155565

  • 发明设计人 XU MANCAI;ZHANG ZHENG;

    申请日2009-03-19

  • 分类号B01J20/28;B01J20/30;B01J20/26;C08F212/36;C08F212/08;C08J9/00;

  • 国家 EP

  • 入库时间 2022-08-21 15:08:38

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