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Method of obtaining and separating valuable metallic elements, specifically from low-grade uranium ores and radioactive liquid wastes

机译:特别是从低品位铀矿和放射性废液中获取和分离有价值的金属元素的方法

摘要

Method of obtaining and separating valuable metallic elements from low-grade uranium ores and radioactive liquid wastes, as used herein, consists in feeding a liquid-solid suspension into the membrane system with the contactor with helical flow, whereas the solid is a known sorbent, preferably activated carbon or complexing agent, preferably soluble polymer, specifically polyacrylic acid. The use of activated carbon as a sorbent, concentration from c = 0.1 g/dcm 3 to c = 0.8 g/dcm 3 , and of the contactor with helical flow, at rotor rate from 800 rpm to 1,200 rpm will mean a virtual absence of the fouling phenomenon and the value of the retention coefficient equal to 60%. On the other hand, when a soluble polymer, specifically polyacrylic acid, is used as a complexing agent, the method as used herein consists in that at the concentration of polyacrylic acid from c = 0.2 g/dcm 2 to c = 0.2 g/dcm 2 , proportion c me /c polymer = 1.4, rotor rate of 1,800 rpm to 2,200 rpm, will mean a virtual absence of the fouling phenomenon and the value of the retention index equal to 98%. For the two options, the time necessary for binding the metallic ion equilibrium content was 6 times shorter compared with the prior art.
机译:如本文所用,从低品位铀矿石和放射性废液中获取并分离出有价值的金属元素的方法,是将液固悬浮液与带有螺旋流的接触器一起送入膜系统,而固体是已知的吸附剂,优选活性炭或络合剂,优选可溶性聚合物,特别是聚丙烯酸。使用活性炭作为吸附剂,浓度从c = 0.1 g / dcm 3到c = 0.8 g / dcm 3,并且在转子转速从800 rpm到1200 rpm时,具有螺旋流的接触器将意味着几乎不存在结垢现象和保留系数的值等于60%。另一方面,当使用可溶性聚合物,特别是聚丙烯酸作为络合剂时,本文所用的方法在于,在聚丙烯酸的浓度为c = 0.2g / dcm 2至c = 0.2g / dcm的情况下。在图2中,c me / c聚合物的比例= 1.4,转子速度为1800rpm至2200rpm,意味着实际上没有结垢现象并且保留指数的值等于98%。对于这两种选择,结合金属离子平衡含量所需的时间比现有技术短6倍。

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