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Biomimetic scaffold for catalytic redox activity and its use

机译:具有催化氧化还原活性的仿生支架及其应用

摘要

The present invention provides a redox catalyst comprising a nanostructure formed by a peptide having the structure of X 1 a-Zn-X 2 b wherein X 1 and X 2 are each independently a pyrophyll interaction Wherein X 1 and X 2 are the same or different and Z is a D or L-type natural or unnatural amino acid or derivative thereof having possible side chains, and Z is a charged D or L having a charged side chain or nucleophilic side chain capable of cross- A and b are the same or different integers from 1 to 10, and n is an integer from 1 to 10, respectively. The peptide nanostructures according to the present invention form a very regular and dense structure and promote chemical electrochemical reactions by the tyrosine residues in the peptides, which can serve as a platform for the production of large area peptide or hybrid films.
机译:本发明提供了一种氧化还原催化剂,其包含由具有X 1 a-Zn-X 2 b结构的肽形成的纳米结构,其中X 1 和X 2 各自独立地为pyrophyll相互作用,其中X 1 和X 2 相同或不同,Z为D或L-类型的具有可能的侧链的天然或非天然氨基酸或其衍生物,Z是带电荷的D或L,其具有能够交叉的带电荷的侧链或亲核性侧链。A和b是1到10的相同或不同的整数,并且n分别是1至10的整数。根据本发明的肽纳米结构形成非常规则和致密的结构,并通过肽中的酪氨酸残基促进化学电化学反应,其可以用作生产大面积肽或杂化膜的平台。

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