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METHOD FOR EXTRACTION OF METALS, NOBLE METALS AND RARE-EARTH METALS FROM WASTE

机译:从废物中提取金属,贵金属和稀土金属的方法

摘要

1. A method of extracting metals, noble metals and rare earth metals from waste, characterized in that the waste and carbon-containing materials (A) in a gas generator (2) of a direct process with a moving bed of bulk material, which has a zone (13) recovery and a zone (7) oxidation, in the presence of alkaline substances under reducing general conditions with a total lambda value of less than 1, they are oxidized with oxygen-containing gases (11), that the resulting synthesis gas is removed in the upper part (16) of the direct process gasifier, and metals, noble metals and rare earth metals in in the form of oxides and / or in elemental form, at least partially bound with alkaline substances, and they are obtained from the technological process by means of physical separation methods in the form of an enriched mixture (B). 2. The method according to claim 1, characterized in that the carbonaceous material (A) and the waste are electronic waste and / or whole electronic devices that have been in use. The method according to claim 1 or 2, characterized in that cable residues and / or other metal-containing powders or solids are also dosed to the carbon-containing material (A) and waste in order to further increase the utilized proportion of metal in the bulk material. The method according to claim 3, characterized in that the metal-containing powders or solids are ash from combustion processes or also oil shale or other naturally occurring carbon-containing materials that contain metals. The method according to claim 1, characterized in that metal oxides, metal carbonates, hydroxy are used as alkaline substances.
机译:1.一种从废物中提取金属,贵金属和稀土金属的方法,其特征在于,在具有散装物料的移动床的直接工艺的气体发生器(2)中,废物和含碳物质(A),在碱性物质的存在下,在还原性一般条件下,总λ值小于1,具有一个区域(13)的回收和一个区域(7)的氧化,它们被含氧气体(11)氧化,合成气在直接工艺气化炉的上部(16)中被除去,并且金属,贵金属和稀土金属以氧化物和/或元素形式存在,至少部分与碱性物质结合,并且它们是通过物理分离方法以浓缩混合物(B)的形式从工艺过程中获得的产物。 2.根据权利要求1所述的方法,其特征在于,所述含碳材料(A)和所述废物是已使用的电子废物和/或整个电子设备。 3.根据权利要求1或2所述的方法,其特征在于,还将电缆残余物和/或其他含金属的粉末或固体计量加入所述含碳材料(A)和废料中,以进一步提高金属在所述含碳材料(A)中的利用率。散装物料。 4.根据权利要求3所述的方法,其特征在于,所述含金属的粉末或固体是来自燃烧过程的灰分,或者是油页岩或其他天然存在的含金属的含金属的材料。 2.根据权利要求1所述的方法,其特征在于,使用金属氧化物,金属碳酸盐,羟基作为碱性物质。

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