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METHOD OF ULTRAHIGH-MOLECULAR WEIGHT POLYETHYLENE (UHMWPE), MODIFIED WITH NANOSIZED TANTALUM PENTOXIDE PARTICLES

机译:纳米五氧化二钽修饰的超高分子量聚乙烯(UHMWPE)的制备方法

摘要

FIELD: chemistry.;SUBSTANCE: invention deals with ultrahigh molecular weight polyethylene (UHMWPE), modified with nanosized particles of tantalum pentoxide. It is applied for the obtaining polycomposite materials, which can be applied in microelectronics, medicine and other fields. It is obtained by the addition of benzyl alcohol to a UHMWPE benzene solution. The formed reaction mixture is mixed at a rate of 400-500 rev/min in boiling for 5-6 hours. Then, it is filtered, washed with benzene, the solvent is distilled. After that, a benzene solution of tantalum pentachloride is added to the reaction mass in a quantity corresponding to the molar ratio of tantalum pentachloride to benzene alcohol, equal to 1:5-5.3. Then the obtained reaction mass is mixed at the same rate in boiling for 3-4 hours, cooled and the target product is separated by filtering, extraction with chloroform and vacuum distillation of the solvent.;EFFECT: extension of application fields of materials with higher physical-mechanical properties.;3 dwg, 2 tbl, 2 ex
机译:领域:化学领域;发明内容:本发明涉及用纳米五氧化二钽颗粒改性的超高分子量聚乙烯(UHMWPE)。用于获得复合材料,可应用于微电子,医药等领域。它是通过将苯甲醇加到UHMWPE苯溶液中获得的。将形成的反应混合物以400-500转/分钟的速率在沸腾中混合5-6小时。然后过滤,用苯洗涤,蒸馏除去溶剂。之后,将五氯化钽的苯溶液以等于五氯化钽与苯醇的摩尔比等于1:5-5.3的量添加到反应物料中。然后将得到的反应物料以相同的速率在沸腾中混合3-4小时,冷却,然后通过过滤,氯仿萃取和溶剂的真空蒸馏来分离目标产物。物理机械性能。; 3 dwg,2 tbl,2 ex

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