COMPREHENSIVE RECOVERY METHOD FOR COMPLEX MATERIAL CONTAINING ARSENIC AND VALUABLE METAL SLAGS

摘要

Disclosed is a comprehensive recovery method for a complex material containing arsenic and valuable metal slags, comprising passing the materials containing arsenic through a primary rotating kiln to volatilize the arsenic, and through a secondary rotating kiln to purify the arsenic, so that an arsenic product containing 99.5% As 2 O 3 is produced; reduction smelting slags from the primary and secondary rotating kilns in a blowing volatilization furnace, with the resultant highly arsenious dust being returned to the primary rotating kiln for treatment, and the slags being used as a raw material in a cement manufactory and a raw material for zinc after undergoing strongly reductive dearsenization and volatilization of zinc in a fuming furnace; the resultant alloy containing arsenic being subjected to basic oxidizing refinement, and the oxidized/refined alloy after dearsenizations containing Pb 72%, Sb 12%, As 2 O 3 0.02%, being sold as a lead-antimony alloy; the basic slags from the refinement, containing As 2 O 3 10%-20%, being subjected to crushing, dissolution in base, and filtration, with the slags thereof being returned to a blowing volatilization furnace for treatment; precipitating tin from the basic solution containing tin and arsenic by blowing in CO 2 , with the filtered tin oxide being sold as a raw material for tin; adding Ca(OH) 2 into the basic filtrate containing arsenic to precipitate arsenic, returning the filtered slags of calcium arsenate to the primary rotating kiln for treatment, and evaporating the remaining basic solution to concentrate and recover the base.