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METHOD FOR PRODUCING DECANOLS BY MEANS OF HYDROGENATING DECENALS

机译:用加氢的癸烯生产癸醇的方法

摘要

The present invention relates to a method for producing at least one decanol by means of hydrogenating at least one decenal, wherein a first hydrogenation is carried out in the liquid phase on a solid first catalyst, wherein the first catalyst contains copper and nickel. The aim of the invention is to provide a method of the type mentioned above, according to which decenals can be hydrogenated into decanols in high yields even after long operating periods. The content of non-reacted decenals in the hydrogenation discharge in particular should be less than 1500 ppm. Said aim is achieved by carrying out the hydrogenation in two steps, which is to say in a first step in a known manner using a catalyst comprising copper, nickel and optionally chromium and/or barium oxide, and subsequently in a second step using a different catalyst that must be free of copper, chromium and nickel.
机译:本发明涉及通过氢化至少一个癸烷来制备至少一种癸醇的方法,其中在固态的第一催化剂上在液相中进行第一氢化,其中第一催化剂包含铜和镍。发明内容本发明的目的是提供一种上述类型的方法,根据该方法即使在长时间的操作之后,癸醛也可以高收率地氢化成癸醇。氢化排出物中未反应的癸醛的含量尤其应小于1500ppm。通过两个步骤进行氢化,即在第一步中以已知方式使用包含铜,镍和任选地铬和/或氧化钡的催化剂,然后在第二步中使用不同的氢化来实现所述目的。催化剂必须不含铜,铬和镍。

著录项

  • 公开/公告号EP2488478B1

    专利类型

  • 公开/公告日2015-11-25

    原文格式PDF

  • 申请/专利权人 EVONIK DEGUSSA GMBH;

    申请/专利号EP20100742161

  • 发明设计人 KAIZIK ALFRED;LUEKEN HANS-GERD;

    申请日2010-08-13

  • 分类号C07C29/17;C07C31/125;

  • 国家 EP

  • 入库时间 2022-08-21 14:50:40

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