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Stable, method of manufacturing small particle size organopolysiloxane emulsion of

机译:稳定的小粒径有机聚硅氧烷乳液的制造方法

摘要

PROBLEM TO BE SOLVED: To provide a method for producing a stable organopolysiloxane emulsion having a small particle size.;SOLUTION: There is provided a method for producing a stable, high-viscosity organopolysiloxane emulsion having a particle size of ≤150 nm, in particular an emulsion polymerization process relating to an easy and cost-effective fast completion of emulsification of organopolysiloxane by using a standard homogenizer and the subsequent polymerization of the organopolysiloxane at a controlled temperature. The method involves a selective combination of a nonionic emulsifier with at least one anionic emulsifier. Importantly, the selective mixture of the nonionic emulsifier and the anionic emulsifier having an HLB value of the mixture near to 12-15 and maintaining a temperature of ≤50°C enables the advantageous production of the stable emulsion having the small particle size with any standard homogenizer without the need for high-pressure homogenizing.;COPYRIGHT: (C)2011,JPO&INPIT
机译:解决的问题:提供一种制备具有小粒径的稳定的有机聚硅氧烷乳液的方法。解决方案:提供一种制备稳定的,粒径为150nm的高粘度有机聚硅氧烷乳液的方法。特别是涉及通过使用标准均化器容易且成本有效地快速完成有机聚硅氧烷的乳化以及随后在受控温度下有机聚硅氧烷的聚合的乳液聚合方法。该方法包括非离子型乳化剂与至少一种阴离子型乳化剂的选择性组合。重要的是,非离子型乳化剂和阴离子型乳化剂的选择性混合物的混合物的HLB值接近12-15,并保持在±50℃的温度下,可以有利地生产具有小粒径的稳定乳化液,且具有任何标准均质机,无需高压均质。;版权所有(C)2011,JPO&INPIT

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