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Method for producing a particulate aggregate, a steam reforming catalyst, method for producing a steam reforming catalyst and a hydrogen production method

机译:制备粒状聚集体的方法,蒸汽重整催化剂,制备蒸汽重整催化剂的方法和制氢方法

摘要

PROBLEM TO BE SOLVED: To provide a method for producing a fine particle aggregate which reduces the amount of a catalyst component to be used without reducing activity by adding a metal oxide carrier as a nucleus internally into a fine particle mixed aggregate produced by the coprecipitation method to substitute the metal oxide carrier for a catalyst component in the aggregate which does not participate largely in reaction, and mitigates aggregation and sintering of the fine particles, a catalyst composed of the fine particle aggregate, and a method for producing hydrogen.;SOLUTION: The method for producing the fine particle aggregate comprises the steps of : suspending a metal oxide powder in a metal compound aqueous solution in which a compound or a plurality of compounds selected from the group consisting of a compound of Zr, Ce, Al, and Y coexists, thereafter mixing an alkali precipitant therewith to coprecipitate a fine particle mixture of a metal hydroxide and/or a metal carbonate, drying the formed precipitate to fix an aggregate of metal hydroxide fine particles and/or metal carbonate fine particles onto the surface of the metal oxide carrier, and further heating the dried precipitate to fix the aggregate of the metal hydroxide fine particles and/or the metal carbonate fine particles onto the surface of the metal oxide carrier.;COPYRIGHT: (C)2012,JPO&INPIT
机译:解决的问题:提供一种通过在共沉淀法制得的细颗粒混合聚集体内部添加金属氧化物载体作为核,从而在不降低活性的情况下减少催化剂成分的使用量的细颗粒聚集体的制造方法。用金属氧化物载体代替不参与反应的骨料中的催化剂组分,并减轻细粒的聚集和烧结,由细粒骨料组成的催化剂以及制氢的方法。制备细粒聚集体的方法包括以下步骤:将金属氧化物粉末悬浮在金属化合物水溶液中,其中一种或多种选自Zr,Ce,Al和Y的化合物的化合物共存,然后将碱沉淀剂与其混合以共沉淀金属氢氧化物和/或金属碳酸盐的细颗粒混合物e,干燥形成的沉淀物以将金属氢氧化物细颗粒和/或金属碳酸盐细颗粒的聚集体固定在金属氧化物载体的表面上,并进一步加热干燥的沉淀物以固定金属氢氧化物细颗粒和/或金属聚集体。将金属碳酸盐细颗粒沉积到金属氧化物载体的表面上。;版权所有:(C)2012,JPO&INPIT

著录项

  • 公开/公告号JP5871312B2

    专利类型

  • 公开/公告日2016-03-01

    原文格式PDF

  • 申请/专利号JP20120003510

  • 发明设计人 松村 安行;

    申请日2012-01-11

  • 分类号B01J23/80;B01J23/60;B01J37/02;B01J37/03;C01B3/32;

  • 国家 JP

  • 入库时间 2022-08-21 14:41:00

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