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Method of manufacturing activated carbon and peroxide decomposition method or decomposition catalyst and carbonyl compound using the method of manufacturing the same, and the activated carbon

机译:活性炭的制造方法及过氧化物的分解方法或使用该催化剂的分解催化剂和羰基化合物的制造方法以及活性炭

摘要

PROBLEM TO BE SOLVED: To provide activated carbon useful as an oxidation catalyst (or a decomposition catalyst).SOLUTION: The hydrogen content, the nitrogen content and the basic surface functional group of activated carbon are regulated to be within ranges of 0.63-0.75 mass%, 2.55-6.50 mass% and 0.88-1.15 meq/g, respectively. A carbonyl compound may be produced by oxidizing a compound having a secondary carbon atom with an oxidant, in the presence of the activated carbon. The compound having a secondary carbon atom may be a secondary alcohol or a compound having a methylene group. The ratio of the activated carbon is about 0.3-1.5 pts.mass to 100 pts.mass of the compound having a secondary carbon atom. The ratio of the peroxide is about 50-1,000 pts.mass to 100 pts.mass of the compound having a secondary carbon atom. The peroxide may be hydrogen peroxide or a peroxyhydrate (for example, urea peroxyhydrate).
机译:解决的问题:提供用作氧化催化剂(或分解催化剂)的活性炭解决方案:活性炭的氢含量,氮含量和基本表面官能团的含量控制在0.63-0.75质量范围内%,2.55-6.50质量%和0.88-1.15meq / g。羰基化合物可以通过在活性炭存在下用氧化剂将具有仲碳原子的化合物氧化来制备。具有仲碳原子的化合物可以是仲醇或具有亚甲基的化合物。活性碳与具有仲碳原子的化合物的100pts质量的比例为约0.3-1.5pts.mass。过氧化物的比例相对于具有仲碳原子的化合物的100pts质量为约50-1,000pts.mass。过氧化物可以是过氧化氢或过氧化物(例如尿素过氧化物)。

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