首页> 外国专利> METHOD FOR CONTINUOUSLY PRODUCING POLYAMIDE OLIGOMERS AND PRODUCING SEMICRYSTALLINE OR AMORPHOUS POLYAMIDES THAT CAN BE THERMOPLASTICALLY PROCESSED

METHOD FOR CONTINUOUSLY PRODUCING POLYAMIDE OLIGOMERS AND PRODUCING SEMICRYSTALLINE OR AMORPHOUS POLYAMIDES THAT CAN BE THERMOPLASTICALLY PROCESSED

机译:连续生产聚酰胺低聚物并生产可热塑加工的半结晶或非晶态聚酰胺的方法

摘要

The invention relates to a process for continuously preparing polyamide oligomers. This comprises continuous conveying of an aqueous solution of polyamide-forming monomers from a reservoir vessel into an oligomerization reactor, heating of the aqueous solution beyond a dissolution or storage temperature, the residence time of the monomer solution in the oligomerization reactor being limited and the pressure or the partial vapor pressure of the water being adjusted such that a conversion of monomers to polyamide oligomers does not exceed a maximum value and/or the polyamide oligomers formed do not phase-separate or spontaneously crystallize in solid form, and continuous discharge of the polyamide oligomers from the oligomerization reactor. A polyamide oligomer preparable by this process can be provided continuously in a mixture with water in a process for preparing a semicrystalline or amorphous, thermoplastically processible polyamide and then postcondensed to give a polyamide. This polyamide can be used for production of moldings by means of injection molding, multicomponent injection molding, injection molding/welding, extrusion, coextrusion, blow molding or thermoforming.
机译:本发明涉及连续制备聚酰胺低聚物的方法。这包括将聚酰胺形成单体的水溶液从储罐连续输送至低聚反应器,将水溶液加热至超过溶解或储存温度,限制了单体溶液在低聚反应器中的停留时间和压力或调节水的分蒸气压,以使单体向聚酰胺低聚物的转化率不超过最大值和/或形成的聚酰胺低聚物不会以固体形式发生相分离或自发结晶,并且会连续排出聚酰胺来自低聚反应器的低聚物。可通过该方法制备的聚酰胺低聚物在制备半结晶或无定形的可热塑性加工的聚酰胺的过程中以与水的混合物连续地提供,然后缩聚以得到聚酰胺。该聚酰胺可以通过注塑,多组分注塑,注塑/焊接,挤出,共挤出,吹塑或热成型用于模制品的生产。

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