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Synthesis of zinc oxide nanocomposites using poly (ionic liquid)

机译:聚离子液体合成氧化锌纳米复合材料

摘要

The method of synthesizing zinc oxide polymer nanocomposite comprises: dissolving equal molar ratios of a sulfonic acid acrylic monomer and a co-monomer with a cross linking agent to form a solution; dispersing the zinc-oxide nanoparticles into the solution; polymerizing the sulfonic acid acrylic monomer with the co-monomer by adding a free radical initiator followed by heating up the solution to a temperature up to 50° C.; raising the temperature up to 60° C. until a zinc oxide polymer nanocomposite is formed; and curing the nanocomposite by heating to at least 105° C. for about 24 hours to form the zinc oxide polymer nanocomposite, wherein the ionic liquid monomer is 2-ccrylamido-2-methyl-1-propanesulfonic acid or a salt thereof and wherein the co-monomer is selected from the group consisting of vinyl pyrrolidone, acrylic acid and N-isopropyl acrylamide monomers.
机译:合成氧化锌聚合物纳米复合材料的方法包括:将等摩尔比例的磺酸丙烯酸类单体和共聚单体与交联剂溶解以形成溶液。将氧化锌纳米粒子分散到溶液中;通过添加自由基引发剂使磺酸丙烯酸类单体与共聚单体聚合,然后将溶液加热至高达50℃的温度;将温度升高至60℃直到形成氧化锌聚合物纳米复合材料;通过加热到至少105℃约24小时来固化所述纳米复合材料以形成所述氧化锌聚合物纳米复合材料,其中所述离子液体单体是2-丙烯酰胺基-2-甲基-1-丙烷磺酸或其盐,并且其中共聚单体选自乙烯基吡咯烷酮,丙烯酸和N-异丙基丙烯酰胺单体。

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