首页> 外国专利> The process of catalysts preparation by immobilization of metaloporfirinas in hidroxissais lamellar, obtaining solid heterogeneous catalysis of a variety of reactions for

The process of catalysts preparation by immobilization of metaloporfirinas in hidroxissais lamellar, obtaining solid heterogeneous catalysis of a variety of reactions for

机译:通过将金属oporfirinas固定在片状Hidroxissais层中,从而获得对各种反应的固体异相催化的催化剂制备过程

摘要

The process of catalysts preparation by immobilization of metaloporfirinas in hidroxissais lamellar, obtaining solid heterogeneous catalysis reactions for various. The present invention is the immobilization of anionic or neutral in metaloporfirinas lamellar hidroxissais synthetic or natural.Refers to as an example, the immobilization of ferroporfirina [Fe (tdfspp)] in the zinc chloride hydroxide where the technique of immobilization under agitation at room temperature was used.The solid catalyst obtained presents great advantages when used in heterogeneous catalysis in comparison to its analogue used in homogeneous catalysis, such as, for example, the improvement in catalytic efficiency and selectivity for different products and the possibility of reuse). The catalyst.Depending on the combination of the metaloporfirinas used in the process of immobilization, the solids obtained may be used as catalysts in the oxidation of organic substrates heterogeneous reactions, reactions of degradation of environmental pollutants, such as dyes, pesticides, fu00e1rm ACOS, among others, or even to reduction reactions.
机译:通过将金属oporfirinas固定在片状Hidroxissais层中来制备催化剂的过程,从而获得各种固体固相催化反应。本发明是在合成的或天然的金属oporfirinas片状hidroxissais中固定阴离子或中性的。例如,在氯化锌氢氧化物中固定ferroporfirina [Fe(tdfspp)],其中室温搅拌下的固定技术为与在均相催化中使用的类似物相比,当用于多相催化中时,所获得的固体催化剂具有很大的优势,例如,提高了催化效率和对不同产物的选择性以及可重复使用的可能性。催化剂。取决于固定过程中使用的金属卟啉的组合,所得固体可用作有机底物非均相反应的氧化,染料,农药等环境污染物的降解反应中的催化剂。除其他外,甚至可以还原反应。

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