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Preparation and characterization of fe-co-zn trimetal oxide nanocomposites and their antibacterial activity and used as adsorbent for remediation of metals in the textile waste water

机译:Fe-Co-zn三金属氧化物纳米复合材料的制备,表征及其抗菌活性,可作为吸附剂用于纺织废水中金属的修复

摘要

A new class of Fe-Co-Zn trimetal oxide nanocomposites was prepared through co-precipitation method and it is used as an adsorbent for the removal of heavy metal Cr (VI) ions from water. The analysis of FTIR, SEM, ED AX were recorded before and after adsorption to explore the number and position of the functional group available for heavy metal binding on to the adsorbent and changes in surface morphology and elemental constitution of the adsorbent. The effect of various factors such as solution pH, initial metal ion concentration, contact time, adsorbent dose and influence of other ions were studied in batch mode experiments. The effects of the presence of one metal ion on the adsorption of the other metal ion were investigated. The experimental results indicated that the uptake capacity of one metal ion was reduced by the presence of the other metal ion. The maximum adsorption of Cr (VI) was observed at pH 6.00 for Fe-Co-Zn trimetal oxide nanocomposites (76 %). The main focus of the work will be to recover, adsorbed the used adsorbent contaminant and regenerate the adsorbent for its reusing is of great importance for environmental and economical reasons, Fe-Co-Zn trimetal oxide nanocomposites recovered by desorption method by using proper desorption agent like H2O by batch mode study. The equilibrium data of the adsorption was well fitted to the Langmuir isotherm. The adsorption process follows the pseudo-second-order kinetic model.The synthesized Fe-Co-Zn trimetal oxide nano particles showed enhanced removal of Cr (VI) ions from water. This work demonstrates that synthesized Fe-Co-Zn trimetal oxide Nano particles can be considered as potential Nano-adsorbent. Fe-Co-Zn trimetal oxide Nano particles have good antibacterial activity.
机译:通过共沉淀法制备了一类新型的Fe-Co-Zn三金属氧化物纳米复合材料,并作为吸附剂从水中去除重金属Cr(VI)离子。吸附前后对FTIR,SEM,ED AX进行分析,以探索可用于重金属与吸附剂结合的官能团的数量和位置,以及吸附剂的表面形态和元素组成的变化。在分批模式实验中研究了溶液pH值,初始金属离子浓度,接触时间,吸附剂剂量以及其他离子的影响等各种因素的影响。研究了一种金属离子的存在对另一种金属离子吸附的影响。实验结果表明,一种金属离子的吸收能力因另一种金属离子的存在而降低。 Fe-Co-Zn三金属氧化物纳米复合材料(76%)在pH 6.00时观察到Cr(VI)的最大吸附。工作的主要重点将是回收,吸附用过的吸附剂污染物并对其进行再利用,因为其再利用对于环境和经济原因具有重要意义。采用合适的脱附剂通过脱附方法回收的Fe-Co-Zn三金属氧化物纳米复合材料就像通过批处理模式研究H2O一样。吸附的平衡数据非常适合Langmuir等温线。吸附过程遵循拟二级动力学模型。合成的Fe-Co-Zn三金属氧化物纳米粒子显示出从水中去除Cr(VI)离子的增强能力。这项工作表明合成的Fe-Co-Zn三金属氧化物纳米颗粒可以视为潜在的纳米吸附剂。 Fe-Co-Zn三金属氧化物纳米颗粒具有良好的抗菌活性。

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