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Method and system for recovering high-purity co2 from gasification gas

机译:从气化气中回收高纯二氧化碳的方法和系统

摘要

To provide a method and a system for recovering CO2 from gasification gas, the method and the system being capable of preventing the recovered CO2 from being contaminated with COS, without repeating cooling and heating operations and without increasing the steam consumption, even when the CO2 recovery ratio is changed in recovering CO2 from gasification gas. Gasification gas being produced in a gasifier 10 and containing CO, CO2, COS and H2S is subjected to dust removal in a scrubber 20. Then, a part of the gas is subjected to a CO shift reaction, in which CO is converted into CO2, in a CO shift reactor 30. Another part of the gasification gas is not subjected to the CO shift reaction by means of a bypass 34, and is mixed with the gas after the CO shift reaction. Thereby, the temperature of the mixture gas is set at 180°C to 300°C, and COS in the mixture gas is converted into H2S in a COS converter 40. The H2S is absorbed and removed by a H2S absorption apparatus 50. Then, CO2 is absorbed and removed by a CO2 absorb apparatus.
机译:为了提供一种从气化气中回收CO 2的方法和系统,该方法和系统即使在回收CO 2的情况下也能够防止回收的CO 2被COS污染,而无需重复进行冷却和加热操作并且不增加蒸汽消耗。从气化气中回收二氧化碳的比率发生了变化。在气化炉10中产生的包含CO,CO2,COS和H2S的气化气体在洗涤器20中进行除尘。然后,一部分气体进行CO转化反应,其中CO转化为CO2,在CO变换反应器30中,另一部分气化气体不通过旁路34进行CO变换反应,而是在CO变换反应之后与气体混合。由此,将混合气体的温度设定为180℃至300℃,并且在COS转化器40中将混合气体中的COS转化为H 2S。H2 S被H 2 S吸收装置50吸收并除去。 CO 2被CO 2吸收设备吸收并除去。

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