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Composite ion exchanger, preferably for sorption of Sr-85, Co-60, Zn-65 radioisotopes and method for producing it

机译:最好用于吸附Sr-85,Co-60,Zn-65放射性同位素的复合离子交换剂及其生产方法

摘要

disclosed wymieniacz ion composite, especially to the sorption of radioisotopes sr 85, - 60, zn - 65, which is characterized by the fact that it is polikondensacyjna resin fenolosulfonowa built with fenolosulfonowego acid and formaldehyde as grains of spherical diameter from 00.01 to 0.25 mm, containing powdered sorbent competent, so sparingly soluble nanoparticles of titanium dioxide, in quantities of from 10 to 30 parts by weight.method of manufacturing composite an ion exchanger should, especially to the sorption of radioisotopes sr 85, - 60, zn - 65, is that the favourable early partially cross-linked acid fenolosulfonowego, at approximately 20u00b0c is 10 to 40 parts by weight of ditle nku titanium in the form of nanotubes, the mass obtained is added with formaldehyde solution again.and the suspension pours into the oil warm to temperature 90u00b0c by intensive mixing, at a rate of approximately 500 rpm. the mixture produced dyspersyjnu0105 diameter of between 0.01 - 0.25 mm, twardnieju0105cych within several minutes, creating hard spherical grains are separated by blotting, drought, temperature 100 degrees for about 1h, odtu0142uszcza organic solvent and then warm sorbent in temperature 60u00b0c.
机译:公开了wymieniacz离子复合物,特别是对放射性同位素sr 85,-60,zn-65的吸附,其特征在于,它是由fenolosulfonowego酸和甲醛制成的polikondensacyjna树脂fenolosulfonowa,球形颗粒的直径为00.01至0.25 mm含有粉状吸附剂,能溶解的少量二氧化钛纳米颗粒,含量为10至30重量份。制造离子交换剂的方法,特别是对放射性同位素sr 85,-60,zn-65的吸附约20 u00b0c时有利的早期部分交联的酸苯并磺磺酸钠为10至40重量份的纳米管形式的微细nku钛,所得物质再加入甲醛溶液。将悬浮液倒入油中通过以大约500 rpm的速率充分混合,将温度升至90°C。混合物产生的直径在0.01-0.25毫米之间的dyspersyjn u0105,在几分钟内变硬,通过吸干,干旱,温度100度,约1h,odt u014105uszcza有机溶剂分离出硬的球形颗粒,然后在温度下加热吸附剂60 u00b0c。

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