New derivatives of 1-aminonaphthaleno-2-carbonitrile, methods for producing them and application, new photosensitizers for the processes of photoinitiated cationic, radical and hybrid polymerization and new photoinitiating systems for the processes of cationic, radical and hybrid photopolymerization

摘要

the invention relates to new derivatives of 1 - aminonaftalen0 - 2 - karbonitrylu of general formula (1), in which r1 is substituent of general formula (2) or substituent of general formula (3), in which the model (2) and (3) substituent r3 selected from group including hydrogen atom, fluorine atom, atom chlo ru, bromine atom, methyl group, the group trifluorometylowu0105, nitrowu0105 group, group metoksylowu0105,group t - butoksylowu0105, group nitrylowu0105, tiometoksylowu0105 group, group metylosulfonylowu0105, trifluorometoksylowu0105 group; r2 means alkyl group such as: - ch3, - c2h5, - c3h7, or group fenylowe - c6h5.the invention also concerns ways of creating new derivatives of 1 - aminonaftaleno - 2 - karbonitrylu, which may find application as a fotosensybilizatory processes fotopolimeryzacji cation, rodnikowej and hybrid.the subject of the invention are also new fotosensybilizatory to fotoinicjowanej cation polymerization processes, rodnikowej and hybrid and new systems fotoinicjuju0105ce containing: a) at least one selected from the group comprising: oniowu0105 salt such as hexafluorophosphate salts jodoniowe dif enylojodoniowy, heksafluoroantymonian difenylojodoniowy,hexafluorophosphate 4 - methyl - 4 '- izopropylodifenylojodoniowy hexafluorophosphate, 4,4' - dimetylodifenylojodoniowy, tetrakis pentafluorofenyloboran 4 - methyl - 4 '- izopropylodifenylojodoniowy, sulfoniowe salts such as hexafluorophosphate triarylosulfoniowy, heksafluoroantymonian triarylosulfoniowy,(b) at least one selected from the group fotosensybilizator new derivatives of 1 - aminonaftaleno - 2 - karbonitrylu of general formula (1).