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Polyamide-elastomer mixtures resistant to hydrolysis, molding parts manufactured from them as well as their use

机译:耐水解的聚酰胺-弹性体混合物,由其制成的成型件及其用途

摘要

Polyamide-elastomer mixture containing a) from 30 to 95% by weight of at least one partially crystalline polyamide with a solution viscosity greater than or equal to 1.75, measured in m-cresol solution, 0.5% by weight at 20 ° C according to DIN EN ISO 307, b) from 5 to 50% by weight of at least one elastomer that is prepared by emulsion polymerization and subsequent spray drying of the latex obtained in emulsion polymerization, c) given the case of 0 to 20% by weight of one or more polyamides with a solution viscosity of less than 1.75, measured in m-cresol solution, 0.5% by weight at 20 ° C according to DIN EN ISO 307, referring the above named indications from% by weight to the total amount of components (a) to (c) and, based on 100 parts by weight of components (a) to (c), from 0 to 100 parts by weight of one or several additives, characterized in that the elastomer b) is prepared by emulsion polymerization of b1) = 55% in weight of at least one conjugated diene, b2) from 5 to 45% by weight of acrylonitrile, b3) in the case of 0 to 5% by weight of one or more radical polymerizable polyfunctional monomers, b4) in the case of 0 to 20% by weight of one or more monomers polymerizable by radicals other than b1) to b3), the indications of% by weight referring to the total amount of components b1) to b4).
机译:聚酰胺弹性体混合物,包含a)30-95%重量的至少一种部分结晶的聚酰胺,溶液粘度大于或等于1.75(在间甲酚溶液中测得),根据DIN在20°C下为0.5%重量EN ISO 307,b)5至50重量%的至少一种弹性体,该弹性体是通过乳液聚合以及随后对乳液聚合中获得的胶乳进行喷雾干燥而制备的; c)假定为0至20重量%根据DIN EN ISO 307,在20°C下于m-甲酚溶液中测得的溶液粘度小于1.75的一种或多种聚酰胺,重量百分比为0.5%,参考上述指示从重量百分比到组分总量( a)至(c),以及基于100重量份的组分(a)至(c),0至100重量份的一种或几种添加剂,其特征在于,弹性体b)通过乳液聚合反应制备。 b1)> = 55%至45%(重量)的至少一种共轭二烯,b2)重量的丙烯腈,b3),在一种或多种自由基聚合性多官能单体的含量为0至5%的情况下,b4),在重量百分比为20%,在一种与多种通过b1)以外的自由基聚合的单体含量的情况下,b4)至b3),重量百分数是指组分b1)至b4)的总量。

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